The calculation of rate coefficients is a discipline of nonlinear science of importance to much of physics, chemistry, engineering, and biology. Fifty years after Kramers' seminal paper on thermally activated barrier crossing, the authors report, extend, and interpret much of our current understanding relating to theories of noise-activated escape, for which many of the notable contributions are originating from the communities both of physics and of physical chemistry. Theoretical as well as numerical approaches are discussed for single- and many-dimensional metastable systems (including fields) in gases and condensed phases. The role of many-dimensional transition-state theory is contrasted with Kramers' reaction-rate theory for moderate-to-strong friction; the authors emphasize the physical situation and the close connection between unimolecular rate theory and Kramers' work for weakly damped systems. The rate theory accounting for memory friction is presented, together with a unifying theoretical approach which covers the whole regime of weak-to-moderate-to-strong friction on the same basis (turnover theory). The peculiarities of noise-activated escape in a variety of physically different metastable potential configurations is elucidated in terms of the mean-first-passage-time technique. Moreover, the role and the complexity of escape in driven systems exhibiting possibly multiple, metastable stationary nonequilibrium states is identified. At lower temperatures, quantum tunneling effects start to dominate the rate mechanism. The early quantum approaches as well as the latest quantum versions of Kramers' theory are discussed, thereby providing a description of dissipative escape events at all temperatures. In addition, an attempt is made to discuss prominent experimental work as it relates to Kramers' reaction-rate theory and to indicate the most important areas for future research in theory and experiment.

Reaction-rate theory: fifty years after Kramers

Part I: Background and Fundamentals Introduction, Mohamed Gad-el-Hak, University of Notre Dame Scaling of Micromechanical Devices, William Trimmer, Standard MEMS, Inc., and Robert H. Stroud, Aerospace Corporation Mechanical Properties of MEMS Materials, William N. Sharpe, Jr., Johns Hopkins University Flow Physics, Mohamed Gad-el-Hak, University of Notre Dame Integrated Simulation for MEMS: Coupling Flow-Structure-Thermal-Electrical Domains, Robert M. Kirby and George Em Karniadakis, Brown University, and Oleg Mikulchenko and Kartikeya Mayaram, Oregon State University Liquid Flows in Microchannels, Kendra V. Sharp and Ronald J. Adrian, University of Illinois at Urbana-Champaign, Juan G. Santiago and Joshua I. Molho, Stanford University Burnett Simulations of Flows in Microdevices, Ramesh K. Agarwal and Keon-Young Yun, Wichita State University Molecular-Based Microfluidic Simulation Models, Ali Beskok, Texas A&M University Lubrication in MEMS, Kenneth S. Breuer, Brown University Physics of Thin Liquid Films, Alexander Oron, Technion, Israel Bubble/Drop Transport in Microchannels, Hsueh-Chia Chang, University of Notre Dame Fundamentals of Control Theory, Bill Goodwine, University of Notre Dame Model-Based Flow Control for Distributed Architectures, Thomas R. Bewley, University of California, San Diego Soft Computing in Control, Mihir Sen and Bill Goodwine, University of Notre Dame Part II: Design and Fabrication Materials for Microelectromechanical Systems Christian A. Zorman and Mehran Mehregany, Case Western Reserve University MEMS Fabrication, Marc J. Madou, Nanogen, Inc. LIGA and Other Replication Techniques, Marc J. Madou, Nanogen, Inc. X-Ray-Based Fabrication, Todd Christenson, Sandia National Laboratories Electrochemical Fabrication (EFAB), Adam L. Cohen, MEMGen Corporation Fabrication and Characterization of Single-Crystal Silicon Carbide MEMS, Robert S. Okojie, NASA Glenn Research Center Deep Reactive Ion Etching for Bulk Micromachining of Silicon Carbide, Glenn M. Beheim, NASA Glenn Research Center Microfabricated Chemical Sensors for Aerospace Applications, Gary W. Hunter, NASA Glenn Research Center, Chung-Chiun Liu, Case Western Reserve University, and Darby B. Makel, Makel Engineering, Inc. Packaging of Harsh-Environment MEMS Devices, Liang-Yu Chen and Jih-Fen Lei, NASA Glenn Research Center Part III: Applications of MEMS Inertial Sensors, Paul L. Bergstrom, Michigan Technological University, and Gary G. Li, OMM, Inc. Micromachined Pressure Sensors, Jae-Sung Park, Chester Wilson, and Yogesh B. Gianchandani, University of Wisconsin-Madison Sensors and Actuators for Turbulent Flows. Lennart Loefdahl, Chalmers University of Technology, and Mohamed Gad-el-Hak, University of Notre Dame Surface-Micromachined Mechanisms, Andrew D. Oliver and David W. Plummer, Sandia National Laboratories Microrobotics Thorbjoern Ebefors and Goeran Stemme, Royal Institute of Technology, Sweden Microscale Vacuum Pumps, E. Phillip Muntz, University of Southern California, and Stephen E. Vargo, SiWave, Inc. Microdroplet Generators. Fan-Gang Tseng, National Tsing Hua University, Taiwan Micro Heat Pipes and Micro Heat Spreaders, G. P. "Bud" Peterson, Rensselaer Polytechnic Institute Microchannel Heat Sinks, Yitshak Zohar, Hong Kong University of Science and Technology Flow Control, Mohamed Gad-el-Hak, University of Notre Dame) Part IV: The Future Reactive Control for Skin-Friction Reduction, Haecheon Choi, Seoul National University Towards MEMS Autonomous Control of Free-Shear Flows, Ahmed Naguib, Michigan State University Fabrication Technologies for Nanoelectromechanical Systems, Gary H. Bernstein, Holly V. Goodson, and Gregory L. Snider, University of Notre Dame Index

The MEMS Handbook

Recent results on theoretical studies of heat conduction in low-dimensional systems are presented. These studies are on simple, yet non-trivial, models. Most of these are classical systems, but some quantum-mechanical work is also reported. Much of the work has been on lattice models corresponding to phononic systems, and some on hard-particle and hard-disc systems. A recently developed approach, using generalized Langevin equations and phonon Green's functions, is explained and several applications to harmonic systems are given. For interacting systems, various analytic approaches based on the Green–Kubo formula are described, and their predictions are compared with the latest results from simulation. These results indicate that for momentum-conserving systems, transport is anomalous in one and two dimensions, and the thermal conductivity κ diverges with system size L as κ ∼ L α. For one-dimensional interacting systems there is strong numerical evidence for a universal exponent α = 1/3, but there is no e...

Heat transport in low-dimensional systems

Stochastic differential equations

We investigate the existence, properties and approach to stationary non-equilibrium states of infinite harmonic crystals. For classical systems these stationary states are, like the Gibbs states, Gaussian measures on the phase space of the infinite system (analogues results are true for quantum systems). Their ergodic properties are the same as those of the equilibrium states: e.g. for ordered periodic crystals they are Bernoulli. Unlike the equilibrium states however they are not “stable” towards perturbations in the potential. We are particularly concerned here with states in which there is a non-vanishing steady heat flux passing through “every point” of the infinite system. Such “superheat-conducting” states are of course only possible in systems in which Fourier's law does not hold: the perfect harmonic crystal being an example of such a system. For a one dimensional system, we find such states (explicitely) as limits, whent→∞, of time evolved initial states μ
 i
 in which the “left” and “right” parts of the infinite crystal are in “equilibrium” at different temperatures, β
 −

 ≠β
 −1
 , and the “middle” part is in an arbitrary state. We also investigate the limit of these stationary (t→∞) states as the coupling strength λ between the “system” and the “reservoirs” goes to zero. In this limit we obtain a product state, where the reservoirs are in equilibrium at temperatures β
 −1
 and β
 −1
 and the system is in the unique stationary state of the reduced dynamics in the weak coupling limit.

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Stationary non-equilibrium states of infinite harmonic systems

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On the Lattice Thermal Conduction

/pdf/energy-flow-in-harmonic-linear-chain-3sb68iz2eu.pdf

Hiroshi Nakazawa

Papers

On the Lattice Thermal Conduction

Energy Flow in Harmonic Linear Chain

A Statistical Mechanical Model of Brownian Motion ---Rubin's Lattice Dynamical Model and Langevin Equation---

Stochastic Burgers' equation in the inviscid limit

Probabilistic Aspects of Equation of Motion of Forced Burgers and Navier-Stokes Turbulence