This article reviews the basic theoretical aspects of graphene, a one-atom-thick allotrope of carbon, with unusual two-dimensional Dirac-like electronic excitations. The Dirac electrons can be controlled by application of external electric and magnetic fields, or by altering sample geometry and/or topology. The Dirac electrons behave in unusual ways in tunneling, confinement, and the integer quantum Hall effect. The electronic properties of graphene stacks are discussed and vary with stacking order and number of layers. Edge (surface) states in graphene depend on the edge termination (zigzag or armchair) and affect the physical properties of nanoribbons. Different types of disorder modify the Dirac equation leading to unusual spectroscopic and transport properties. The effects of electron-electron and electron-phonon interactions in single layer and multilayer graphene are also presented.

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The electronic properties of graphene

Weyl and Dirac semimetals are three-dimensional phases of matter with gapless electronic excitations that are protected by topology and symmetry. As three-dimensional analogs of graphene, they have generated much recent interest. Deep connections exist with particle physics models of relativistic chiral fermions, and, despite their gaplessness, to solid-state topological and Chern insulators. Their characteristic electronic properties lead to protected surface states and novel responses to applied electric and magnetic fields. The theoretical foundations of these phases, their proposed realizations in solid-state systems, and recent experiments on candidate materials as well as their relation to other states of matter are reviewed.

Weyl and Dirac semimetals in three-dimensional solids

This article reviews the physics of high-temperature superconductors from the point of view of the doping of a Mott insulator. The basic electronic structure of cuprates is reviewed, emphasizing the physics of strong correlation and establishing the model of a doped Mott insulator as a starting point. A variety of experiments are discussed, focusing on the region of the phase diagram close to the Mott insulator (the underdoped region) where the behavior is most anomalous. The normal state in this region exhibits pseudogap phenomenon. In contrast, the quasiparticles in the superconducting state are well defined and behave according to theory. This review introduces Anderson's idea of the resonating valence bond and argues that it gives a qualitative account of the data. The importance of phase fluctuations is discussed, leading to a theory of the transition temperature, which is driven by phase fluctuations and the thermal excitation of quasiparticles. However, an argument is made that phase fluctuations can only explain pseudogap phenomenology over a limited temperature range, and some additional physics is needed to explain the onset of singlet formation at very high temperatures. A description of the numerical method of the projected wave function is presented, which turns out to be a very useful technique for implementing the strong correlation constraint and leads to a number of predictions which are in agreement with experiments. The remainder of the paper deals with an analytic treatment of the $t\text{\ensuremath{-}}J$ model, with the goal of putting the resonating valence bond idea on a more formal footing. The slave boson is introduced to enforce the constraint againt double occupation and it is shown that the implementation of this local constraint leads naturally to gauge theories. This review follows the historical order by first examining the U(1) formulation of the gauge theory. Some inadequacies of this formulation for underdoping are discussed, leading to the SU(2) formulation. Here follows a rather thorough discussion of the role of gauge theory in describing the spin-liquid phase of the undoped Mott insulator. The difference between the high-energy gauge group in the formulation of the problem versus the low-energy gauge group, which is an emergent phenomenon, is emphasized. Several possible routes to deconfinement based on different emergent gauge groups are discussed, which leads to the physics of fractionalization and spin-charge separation. Next the extension of the SU(2) formulation to nonzero doping is described with a focus on a part of the mean-field phase diagram called the staggered flux liquid phase. It will be shown that inclusion of the gauge fluctuation provides a reasonable description of the pseudogap phase. It is emphasized that $d$-wave superconductivity can be considered as evolving from a stable U(1) spin liquid. These ideas are applied to the high-${T}_{c}$ cuprates, and their implications for the vortex structure and the phase diagram are discussed. A possible test of the topological structure of the pseudogap phase is described.

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Doping a Mott insulator: Physics of high-temperature superconductivity

We provide a broad review of fundamental electronic properties of two-dimensional graphene with the emphasis on density and temperature dependent carrier transport in doped or gated graphene structures. A salient feature of our review is a critical comparison between carrier transport in graphene and in two-dimensional semiconductor systems (e.g. heterostructures, quantum wells, inversion layers) so that the unique features of graphene electronic properties arising from its gap- less, massless, chiral Dirac spectrum are highlighted. Experiment and theory as well as quantum and semi-classical transport are discussed in a synergistic manner in order to provide a unified and comprehensive perspective. Although the emphasis of the review is on those aspects of graphene transport where reasonable consensus exists in the literature, open questions are discussed as well. Various physical mechanisms controlling transport are described in depth including long- range charged impurity scattering, screening, short-range defect scattering, phonon scattering, many-body effects, Klein tunneling, minimum conductivity at the Dirac point, electron-hole puddle formation, p-n junctions, localization, percolation, quantum-classical crossover, midgap states, quantum Hall effects, and other phenomena.

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Electronic transport in two-dimensional graphene

Introduction * Scaling and Dimensional Analysis * Power Laws in Statistical Physics * Some Important Questions * Historical Development * Exercises How Phase Transitions Occur In Principle * Review of Statistical Mechanics * The Thermodynamic Limit * Phase Boundaries and Phase Transitions * The Role of Models * The Ising Model * Analytic Properties of the Ising Model * Symmetry Properties of the Ising Model * Existence of Phase Transitions * Spontaneous Symmetry Breaking * Ergodicity Breaking * Fluids * Lattice Gases * Equivalence in Statistical Mechanics * Miscellaneous Remarks * Exercises How Phase Transitions Occur In Practice * Ad Hoc Solution Methods * The Transfer Matrix * Phase Transitions * Thermodynamic Properties * Spatial Correlations * Low Temperature Expansion * Mean Field Theory * Exercises Critical Phenomena in Fluids * Thermodynamics * Two-Phase Coexistence * Vicinity of the Critical Point * Van der Waals Equation * Spatial Correlations * Measurement of Critical Exponents * Exercises Landau Theory * Order Parameters * Common Features of Mean Field Theories * Phenomenological Landau Theory * Continuous Phase Transitions * Inhomogeneous Systems * Correlation Functions * Exercises Fluctuations and the Breakdown of Landau Theory * Breakdown of Microscopic Landau Theory * Breakdown of Phenomenological Landau Theory * The Gaussian Approximation * Critical Exponents * Exercises Scaling in Static, Dynamic and Non-Equilibrium Phenomena * The Static-Scaling Hypothesis * Other Forms of the Scaling Hypothesis * Dynamic Critical Phenomena * Scaling in the Approach to Equilibrium * Summary The Renormalisation Group * Block Spins * Basic Ideas of the Renormalisation Group * Fixed Points * Origin of Scaling * RG in Differential Form * RG for the Two Dimensional Ising Model * First Order Transitions and Non-Critical Properties * RG for the Correlation Function * Crossover Phenomena * Correlations to Scaling * Finite Size Scaling Anomalous Dimensions Far From Equilibrium * Introduction * Similarity Solutions * Anomalous Dimensions in Similarity Solutions * Renormalisation * Perturbation Theory for Barenblatts Equation * Fixed Points * Conclusion Continuous Symmetry * Correlation in the Ordered Phase * Kosterlitz-Thouless Transition Critical Phenomena Near Four Dimensions * Basic Idea of the Epsilon Expansion * RG for the Gaussian Model * RG Beyond the Gaussian Approximation * Feyman Diagrams * The RG Recursion Relations * Conclusion

Lectures On Phase Transitions And The Renormalization Group

The low-energy theory of interacting electrons on graphene's two-dimensional honeycomb lattice is derived and discussed. In particular, the Hubbard model in the large-N limit is shown to have a semimetal-antiferromagnetic insulator quantum critical point in the universality class of the Gross-Neveu model. The same equivalence is conjectured to hold in the physical case N=2, and its consequences for various physical quantities are examined. The effects of the long-range Coulomb interaction and the magnetic field are discussed.

https://arxiv.org/pdf/cond-mat/0606195.pdf

Interactions and phase transitions on graphene's honeycomb lattice.

The general low-energy theory of electrons interacting via repulsive short-range interactions on graphene's honeycomb lattice at half-filling is presented. The exact symmetry of the Lagrangian with local quartic terms for the Dirac four-component field dictated by the lattice is identified as ${D}_{2}\ifmmode\times\else\texttimes\fi{}{U}_{c}(1)\ifmmode\times\else\texttimes\fi{}\text{time}$ reversal, where ${D}_{2}$ is the dihedral group, and ${U}_{c}(1)$ is a subgroup of the ${\text{SU}}_{c}(2)$ ``chiral'' group of the noninteracting Lagrangian that represents translations in Dirac language. The Lagrangian describing spinless particles respecting this symmetry is parametrized by six independent coupling constants. We show how first imposing the rotational, then Lorentz, and finally chiral symmetry to the quartic terms---in conjunction with the Fierz transformations---eventually reduces the set of couplings to just two, in the ``maximally symmetric'' local interacting theory. We identify the two critical points in such a Lorentz and chirally symmetric theory as describing metal-insulator transitions into the states with either time reversal or chiral symmetry being broken. The latter is proposed to govern the continuous transition in both the Thirring and Nambu-Jona-Lasinio models in $2+1$ dimensions and with a single Dirac field. In the site-localized ``atomic'' limit of the interacting Hamiltonian, under the assumption of emergent Lorentz invariance, the low-energy theory describes the continuous transitions into the insulator with either a finite Haldane's (circulating currents) or Semenoff's (staggered density) masses, both in the universality class of the Gross-Neveu model. The simple picture of the metal-insulator transition on a honeycomb lattice emerges at which the residue of the quasiparticle pole at the metallic and the mass gap in the insulating phase both vanish continuously as the critical point is approached. In contrast to these two critical quantities, we argue that the Fermi velocity is noncritical as a consequence of the dynamical exponent being fixed to unity by the emergent Lorentz invariance near criticality. Possible effects of the long-range Coulomb interaction and the critical behavior of the specific heat and conductivity are discussed.

Theory of interacting electrons on the honeycomb lattice

A new algorithm of quantum Monte Carlo simulations designed to detect very weak magnetic order allows high-resolution studies of the correlation between magnetic order and electrical insulation in Mott insulators. Specific investigations of the Hubbard model on honeycomb lattice---a paradigmatic model for Mott insulators---show that the correlation emerges through a continuous quantum phase transition belonging to a new universality class.

Pinning the Order: The Nature of Quantum Criticality in the Hubbard Model on Honeycomb Lattice

We numerically investigate the critical behavior of the Hubbard model on the honeycomb and the $\ensuremath{\pi}$-flux lattice, which exhibits a direct transition from a Dirac semimetal to an antiferromagnetically ordered Mott insulator. We use projective auxiliary-field quantum Monte Carlo simulations and a careful finite-size scaling analysis that exploits approximately improved renormalization-group-invariant observables. This approach, which is successfully verified for the three-dimensional XY transition of the Kane-Mele-Hubbard model, allows us to extract estimates for the critical couplings and the critical exponents. The results confirm that the critical behavior for the semimetal to Mott insulator transition in the Hubbard model belongs to the Gross-Neveu-Heisenberg universality class on both lattices.

Fermionic quantum criticality in honeycomb and π -flux Hubbard models: Finite-size scaling of renormalization-group-invariant observables from quantum Monte Carlo

We argue that the unscreened Coulomb interaction in graphene provides a positive, universal, and logarithmic correction to scaling of zero-temperature conductivity with frequency. The combined effect of the disorder due to wrinkling of the graphene sheet and the long-range electron-electron interactions is a finite positive contribution to the dc conductivity. This contribution is disorder strength dependent and thus nonuniversal. The low-energy behavior of such a system is governed by the line of fixed points at which both the interaction and disorder are finite, and the density of states is exactly linear. An estimate of the typical random vector potential representing ripples in graphene brings the theoretical value of the minimal conductivity into the vicinity of 4e 2 /h.

Igor F. Herbut

Papers

Interactions and phase transitions on graphene's honeycomb lattice.

Theory of interacting electrons on the honeycomb lattice

Pinning the Order: The Nature of Quantum Criticality in the Hubbard Model on Honeycomb Lattice

Fermionic quantum criticality in honeycomb and π -flux Hubbard models: Finite-size scaling of renormalization-group-invariant observables from quantum Monte Carlo

Coulomb interaction, ripples, and the minimal conductivity of graphene.