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Irina V. Tyulpina
Researcher at Moscow State University
Publications - 7
Citations - 232
Irina V. Tyulpina is an academic researcher from Moscow State University. The author has contributed to research in topics: Electron paramagnetic resonance & Radical. The author has an hindex of 5, co-authored 7 publications receiving 220 citations.
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Experimental evidence for the formation of HXeCCH: The first hydrocarbon with an inserted rare-gas atom
TL;DR: Combined FTIR and EPR studies of acetylene irradiated with fast electrons in a solid xenon matrix provide experimental evidence for the formation of HXeCCH, a novel-type organic molecule with an inserted rare-gas atom.
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Stabilisation and reactions of aliphatic radical cations produced by fast electron irradiation in solid argon matrices
TL;DR: In this paper, the stability and reactions of radical cations produced by irradiation of various aliphatic molecules (ethers and carbonyl compounds) in argon matrices in the presence of electron scavengers at 10-16 K were studied.
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Reactions of H atoms produced by electron irradiation of benzene in solid xenon: IR spectrum of cylohexadienyl radical and possible involvement of HXeC6H5
Vladimir I. Feldman,Fedor F. Sukhov,Elizaveta A. Logacheva,Aleksei Yu. Orlov,Irina V. Tyulpina,Daniil A. Tyurin +5 more
TL;DR: In this article, chemical reactions induced by fast electron irradiation of benzene in solid xenon were studied by EPR and FTIR spectroscopy, and a computationally stable molecule HXeC6H5 was not found experimentally, which means that it was either not formed or not stabilized under the experimental conditions used.
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Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K : formation of xenon-containing molecules and radicals
Vladimir I. Feldman,Vladimir I. Feldman,Fedor F. Sukhov,A.Yu. Orlov,Irina V. Tyulpina,E. A. Logacheva,E. A. Logacheva,Daniil A. Tyurin +7 more
TL;DR: The formation of HXeCCH molecules and radicals resulting from chemical reactions in solid xenon-acetylene systems irradiated with fast electrons was studied by low-temperature IR and EPR spectroscopies as discussed by the authors.
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Stabilization and isomerization of radical cations generated by fast electron irradiation of unsaturated organic molecules in a solid argon matrix
Vladimir I. Feldman,Vladimir I. Feldman,Fedor F. Sukhov,A.Yu. Orlov,Irina V. Tyulpina,V.K. Ivanchenko +5 more
TL;DR: In this paper, the role of molecular structure of organic radical cations in excess energy relaxation was discussed, and it was found that the radical cation of cis -2-butene, trans -2butene and ethyl vinyl ether resulting from highly exothermic hole transfer (excess energy>6 eV) underwent effective relaxation in an argon matrix.