A brief history and review of geopolymer technology is presented with the aim of introducing the technology and the vast categories of materials that may be synthesized by alkali-activation of aluminosilicates. The fundamental chemical and structural characteristics of geopolymers derived from metakaolin, fly ash and slag are explored in terms of the effects of raw material selection on the properties of geopolymer composites. It is shown that the raw materials and processing conditions are critical in determining the setting behavior, workability and chemical and physical properties of geopolymeric products. The structural and chemical characteristics that are common to all geopolymeric materials are presented, as well as those that are determined by the specific interactions occurring in different systems, providing the ability for tailored design of geopolymers to specific applications in terms of both technical and commercial requirements.

Geopolymer technology: the current state of the art

: Geochemical reaction path modeling is useful for rapidly assessing the extent of water-aqueous-gas interactions both in natural systems and in industrial processes. Modeling of some systems, such as those at low temperature with relatively high hydrologic flow rates, or those perturbed by the subsurface injection of industrial waste such as CO2 or H2S, must account for the relatively slow kinetics of mineral-gas-water interactions. We have therefore compiled parameters conforming to a general Arrhenius-type rate equation, for over 70 minerals, including phases from all the major classes of silicates, most carbonates, and many other non-silicates. These data have been added to a computer code that simulates an infinitely well-stirred batch reactor, allowing computation of mass transfer as a function of time. Actual equilibration rates are expected to be much slower than those predicted by the selected computer code, primarily because actual geochemical processes commonly involve flow through porous or fractured media, wherein the development of concentration gradients in the aqueous phase near mineral surfaces, which results in decreased absolute chemical affinity and slower reaction rates. Further differences between observed and computed reaction rates may occur because of variables beyond the scope of most geochemical simulators, such as variation in grain size, aquifer heterogeneity, preferred fluid flow paths, primary and secondary mineral coatings, and secondary minerals that may lead to decreased porosity and clogged pore throats.

/pdf/a-compilation-of-rate-parameters-of-water-mineral-1o9qltikkk.pdf

A Compilation of Rate Parameters of Water-Mineral Interaction Kinetics for Application to Geochemical Modeling

This review provides a comprehensive evaluation of the state-of-knowledge of radiation effects in crystalline ceramics that may be used for the immobilization of high-level nuclear waste and plutonium. The current understanding of radiation damage processes, defect generation, microstructure development, theoretical methods, and experimental methods are reviewed. Fundamental scientific and technological issues that offer opportunities for research are identified. The most important issue is the need for an understanding of the radiation-induced structural changes at the atomic, microscopic, and macroscopic levels, and the effect of these changes on the release rates of radionuclides during corrosion.

https://www.cambridge.org/core/services/aop-cambridge-core/content/view/09D70E1FB1A625EC09BB98883C3A5ED3/S0884291400044411a.pdf/div-class-title-radiation-effects-in-crystalline-ceramics-for-the-immobilization-of-high-level-nuclear-waste-and-plutonium-div.pdf

Radiation effects in crystalline ceramics for the immobilization of high-level nuclear waste and plutonium

The crustal Urey cycle of CO2 involving silicate weathering and metamorphism acts as a dynamic climate buffer. In this cycle, warmer temperatures speed silicate weathering and carbonate formation, reducing atmospheric CO2 and thereby inducing global cooling. Over long periods of time, cycling of CO2 into and out of the mantle also dynamically buffers CO2. In the mantle cycle, CO2 is outgassed at ridge axes and island arcs, while subduction of carbonatized oceanic basalt and pelagic sediments returns CO2 to the mantle. Negative feedback is provided because the amount of basalt carbonatization depends on CO2 in seawater and therefore on CO2 in the air. On the early Earth, processes involving tectonics were more vigorous than at present, and the dynamic mantle buffer dominated over the crustal one. The mantle cycle would have maintained atmospheric and oceanic CO2 reservoirs at levels where the climate was cold in the Archean unless another greenhouse gas was important. Reaction of CO2 with impact ejecta and its eventual subduction produce even lower levels of atmospheric CO2 and small crustal carbonate reservoirs in the Hadean. Despite its name, the Hadean climate would have been freezing unless tempered by other greenhouse gases.

https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/2000JE001247

Carbon dioxide cycling and implications for climate on ancient Earth

https://notendur.hi.is/sigrg/PDF-files/Oelkers-Gislason2001.pdf

The mechanism, rates and consequences of basaltic glass dissolution: I. An experimental study of the dissolution rates of basaltic glass as a function of aqueous Al, Si and oxalic acid concentration at 25°C and pH = 3 and 11

J.L. Crovisier

Papers

Dissolution of basaltic glass in seawater: Mechanism and rate

Kinetic aspects of basaltic glass dissolution at 90°C: role of aqueous silicon and aluminium

Nature and role of natural alteration gels formed on the surface of ancient volcanic glasses (Natural analogs of waste containment glasses)

Dissolution of subglacial volcanic glasses from Iceland: laboratory study and modelling

Geochemical evolution of basaltic rocks subjected to weathering: Fate of the major elements, rare earth elements, and thorium