A comprehensive review is presented of the extractive metallurgy of rare earths. The topics covered are: world rare earth resources and production; ore processing and separation of individual rare earths; reduction, refining, and ultrapurification of rare earth elements; methods for rare earth materials analysis; and a selection of the numerous rare earth applications. World rare earth reserves are abundant and would last for well beyond the next century. However, all of the 16 naturally occurring rare earth elements are not equally distributed in the ore minerals. This, compounded with the problems specific to the isolation and recovery of each of the rare earths, sets the stage for an unequal rare earth availability. The close chemical similarity of rare earths looses its importance when divergent physical properties determine the processes for rare earth element reduction and refining. The rare earth metals, alloys, and compounds have been as pure as could be determined. Finally, the commercial...

Extractive Metallurgy of Rare Earths

Magnetooptical garnets combine high Faraday rotation with low optical losses in the near infrared region where optical communication via glass ?ber is established. In this spectral range garnets are the only materials discussed to realize nonreciprocal devices as optical isolators and circulators. Although such devices are available as microoptical components, practical versions of their integrated counterparts are still lacking. Numerous concepts have been developed theoretically many of which are tested experimentally. This paper presents an overview of the state of the art of the applications of garnet films in integrated optics. Also the technique of combining garnets with semiconductor materials is shortly discussed.

Applications of magneto-optical waveguides in integrated optics: review

The growth of magnetic garnets by liquid phase epitaxy

Single crystals of Gd3Ga3Al2O12 : Ce with different codopants were successfully grown using the Czochralski technique. Optical and scintillation properties of these codoped crystals were studied in detail including absorption, photoluminescence excitation and emission, decay time and thermoluminescence. This study revealed that while boron codoping improves the scintillation light output and energy resolution and decreases self-absorption in these crystals, calcium codoping affects their properties in the opposite manner. In addition to antisite defects, the effect of room temperature trap centres on the sensitivity of these crystals to light exposure is also reported for the first time. Light sensitivity was also found to be affected with the incorporation of codopants in the lattice. The effect of annealing in oxidizing and reducing atmospheres on the scintillation and optical properties of differently codoped crystals was also investigated in detail in order to better understand the defect structure of these crystals. All these measurements together are used to explain the effect of codoping on the crystal field and defect structure of these crystals.

http://iopscience.iop.org/article/10.1088/0022-3727/46/47/475302/pdf

J.W. Nielsen

Papers

The growth of magnetic garnets by liquid phase epitaxy

The elimination of defects in Czochralski grown rare-earth gallium garnets

Crystal growth and phase equilibrium studies in the system (R.E.)2O3Fe2O3

Growth of transparent, striation-free Ba2NaNb5O15 single crystals by a low-thermal-gradient Czochralski technique

Liquid encapsulated growth of GaP from non-stoichiometric melts