J
Jaan Saame
Researcher at University of Tartu
Publications - 30
Citations - 1298
Jaan Saame is an academic researcher from University of Tartu. The author has contributed to research in topics: Phosphazene & Enantioselective synthesis. The author has an hindex of 14, co-authored 29 publications receiving 986 citations. Previous affiliations of Jaan Saame include National Academy of Sciences of Ukraine.
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Journal ArticleDOI
Equilibrium acidities of superacids.
Agnes Kütt,Toomas Rodima,Jaan Saame,Elin Raamat,Vahur Mäemets,Ivari Kaljurand,Ilmar A. Koppel,Romute Yu. Garlyauskayte,Yurii L. Yagupolskii,Lev M. Yagupolskii,Eduard Bernhardt,Helge Willner,Ivo Leito +12 more
TL;DR: The current scale is complementary to the well-known H(0) scale in the information that it provides and is expected to be a useful tool in design, use, and further acidity measurements of superacidic molecules.
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On the Basicity of Organic Bases in Different Media
Sofja Tshepelevitsh,Agnes Kütt,Märt Lõkov,Ivari Kaljurand,Jaan Saame,Agnes Heering,Paul G. Plieger,Robert Vianello,Ivo Leito +8 more
TL;DR: In this article, the authors proposed a method to detect the presence of aniline in the human body and to identify the most likely source of such anisotropic molecules, which can be used as a biomarker for cancer.
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Acidities of strong neutral Brønsted acids in different media
Elin Raamat,Karl Kaupmees,Gea Ovsjannikov,Aleksander Trummal,Agnes Kütt,Jaan Saame,Ivar Koppel,Ivari Kaljurand,Lauri Lipping,Toomas Rodima,Viljar Pihl,Ilmar A. Koppel,Ivo Leito +12 more
TL;DR: In this article, the acidity of different families of acids is examined in media of different physical and chemical nature: water, acetonitrile (AN), 1,2-dichloroethane (DCE), and the gas phase, with special emphasis on strong acids.
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Basicity Limits of Neutral Organic Superbases
TL;DR: The potential limits of superbasicity achievable with different families of neutral bases by expanding the molecular framework are explored using DFT computations and some of the considered bases are expected to reach gas-phase basicity around 370 kcal mol(-1), thus being the most basic neutral bases ever reported.
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Basicity of Phosphanes and Diphosphanes in Acetonitrile
TL;DR: In this article, the basicity of mono-and diphosphanes in acetonitrile was analyzed and compared with that of amines of similar structure, and it was shown that a remarkably stronger change in basicity can be observed in the amines in comparison with the phosphanes when alkyl groups are replaced by aryl groups.