J
James A. Golen
Researcher at University of California, San Diego
Publications - 149
Citations - 2751
James A. Golen is an academic researcher from University of California, San Diego. The author has contributed to research in topics: Crystal structure & Chemistry. The author has an hindex of 29, co-authored 132 publications receiving 2451 citations. Previous affiliations of James A. Golen include Lafayette College & Northwest University (United States).
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Synthesis, structure, and magnetic properties of valence ambiguous dinuclear antiferromagnetically coupled cobalt and ferromagnetically coupled iron complexes containing the chloranilate(2-) and the significantly stronger coupling chloranilate(*3-) radical trianion.
TL;DR: The dinuclear compound bridged chloranilates (CA2- or CA*3-) were isolated and characterized by X-ray crystallography, electrochemistry, magnetism, and EPR spectroscopy and are confirmed from both solid-state magnetic and solution EPR data.
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Palladium-catalyzed asymmetric phosphination. Scope, mechanism, and origin of enantioselectivity.
Natalia F. Blank,Jillian R. Moncarz,Tim J. Brunker,Corina Scriban,Brian J. Anderson,Omar Amir,David S. Glueck,Lev N. Zakharov,James A. Golen,Christopher D. Incarvito,Arnold L. Rheingold +10 more
TL;DR: Kinetic studies of the first-order reductive elimination of 5 were consistent with a Curtin-Hammett-Winstein-Holness (CHWH) scheme, in which pyramidal inversion at the phosphido ligand was much faster than P-C bond formation.
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A labile and catalytically active imidazol-2-yl fragment system.
Valentín Miranda-Soto,Douglas B. Grotjahn,Andrew L. Cooksy,James A. Golen,Curtis E. Moore,Arnold L. Rheingold +5 more
TL;DR: The N H function of a protic NHC complex (A or D ; Scheme 1) could include transformations that may possibly involve both the metal center and at one ring nitrogen of the NHC ligand are much less common, 5c,e–g] and are limited to protIC NHC complexes or their conjugated bases.
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Chiral Palladium(0) trans -Stilbene Complexes: Synthesis, Structure, and Oxidative Addition of Phenyl Iodide
Tim J. Brunker,Natalia F. Blank,Jillian R. Moncarz,Corina Scriban,Brian J. Anderson,David S. Glueck,Lev N. Zakharov,James A. Golen,Roger D. Sommer,Christopher D. Incarvito,Arnold L. Rheingold +10 more
TL;DR: The rate of oxidative addition of phenyl iodide to the stilbene complexes, which gave Pd(diphos*)(Ph)(I), depended on the ligand and was markedly faster than oxidative addition to mixtures of Pd (dba)2 and diphos*.
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Three new pseudohalide bridged dinuclear Zn(II), Cd(II) complexes of pyrimidine derived Schiff base ligands: Synthesis, crystal structures and fluorescence studies
Sangita Ray,Saugata Konar,Atanu Jana,Sankar Jana,Amarendra Patra,Sudipta Chatterjee,James A. Golen,Arnold L. Rheingold,Sudhanshu Sekhar Mandal,Susanta Kumar Kar +9 more
TL;DR: One dinuclear Zn(II) complex was synthesized and characterized by elemental analyses, IR, 1 H NMR, fluorescence spectroscopy and single crystal X-ray crystallography.