The colloidal structure of bitumen: Consequences on the rheology and on the mechanisms of bitumen modification

Polymer modified asphalt binders

http://www.diva-portal.org/smash/get/diva2:711917/FULLTEXT01

Polymer modification of bitumen : Advances and challenges

Investigation of rutting performance of asphalt mixtures containing polymer modifiers

1.Introduction to Composite Materials 2. Macrochemical Behavior of a Lamina 3.Micromechanical Behavior of a Lamina 4.Macromechanical Behavior of a Laminate 5.Bending, Buckling, and Vibration of Laminated Plates 6.Other Analysis and Behavior Topics 7.Introduction to Design of Composite Structures Appendix A.Matrices and Tensors Appendix B.Maxima and Minima of Functions of a Single Variable Appendix C.Typical Stress-Strain Curves Appendix D.Governing Equations for Beam Equilibrium and Plate Equilibrium, Buckling, and Vibration Index

/pdf/mechanics-of-composite-materials-4uyw5i9ck8.pdf

Mechanics of composite materials

The styrene-butadiene-styrene ~SBS! triblock copolymer was used to modify the asphalt binder. The morphology and engi- neering properties of the binders were investigated using transmission electron microscopy ~TEM!, rotational viscometer, and dynamic shear rheometer. The morphology of polymer-modified asphalt was described by the SBS concentration and the presence of microstructure of the copolymer. When the SBS concentration increased, the copolymer gradually became the dominant phase, and the transition was followed by a change in engineering properties of SBS-modified asphalt. Results from TEM showed that depending on the asphalt and copolymer source, a variety of morphology can be found. The SBS-modified binders might show a continuous asphalt phase with dispersed SBS particles, a continuous polymer phase with dispersed asphalt globules, or two interlocked continuous phases. The optimum SBS content was determined based on the formation of the critical network between asphalt and polymer. Because of this network formation, the binders showed a large increase in the complex modulus that indicates resistance to rutting. At low SBS concentrations, the Kerner model was found to be appropriate to estimate the rheological properties of SBS-modified asphalt. An adapted Kerner equation was proposed in this study to predict the complex modulus of modified asphalt at high SBS concentrations.

/pdf/asphalt-modified-by-styrene-butadiene-styrene-triblock-3mkc7a5i0b.pdf

Asphalt modified by styrene-butadiene-styrene triblock copolymer: Morphology and model

This paper investigates the reinforcement mechanism of bitumen mixed with fibers. Fibers including cellulose, rock wool and polyester types were added to bitumen. The viscosity, toughness and tenacity, microscopy and rheological tests were conducted to characterize the engineering properties of bitumen-fiber mastics. Test results indicate that the reinforcing effect increases with increasing fibers up to a critical fraction. With higher mixing temperatures, there is a higher viscosity ratio of mastic to bitumen. The tensile strength of bitumen-fiber mastics also increases with increasing fiber concentrations because the fibers carry parts of tensile loads. With the increasing tensile strength, it is implied that there is a good adhesion between bitumen and fibers. Scanning electron micrographs show that fibers reinforce bitumen through a three dimensional structure. However, there is a critical fiber fraction when fibers start to interact with each other, resulting in lower toughness. The optimum fiber content is dependent on fiber type, length and diameter.

Mechanism and behavior of bitumen strength reinforcement using fibers

The purpose of this study was to characterize the mechanical behavior of asphalt modified by styrene–butadiene–styrene (SBS) and sulfur. Viscosity, microscopy, and rheological tests were conducted to understand the engineering properties of the polymer-modified asphalt (PMA). Without the addition of sulfur, the polymer-modified asphalt was microheterogeneous and was made up of two distinct finely interlocked phases, especially at high SBS concentrations. After the addition of sulfur, the PMA was observed to have smaller asphalt domains and a fairly homogeneous dispersion of the asphalt in the SBS matrix. The compatibility between polymer and asphalt produced an elastic network into the asphalt. The addition of sulfur resulted in an excellent elastic system and substantially increased the rheological properties of the PMA. Because of the colloidal nature of asphalt cements, their engineering properties were greatly improved because of the reinforcement of the SBS polymer and the physical-chemical interaction between SBS and asphalt. The difference in the softening point between the top and bottom layers decreased significantly, and elastic recovery increased when was sulfur was present. A viscoelastic model was examined and shown to be appropriate for predicting the rheological properties ofthe asphalt–SBS blend mixed with sulfur. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2817–2825, 2007

/pdf/fundamental-characterization-of-sbs-modified-asphalt-mixed-6lnerobrb4.pdf

Fundamental Characterization of SBS- Modified Asphalt Mixed with Sulfur

Engineering properties and performance of asphalt mixtures incorporating steel slag

A recycling agent is commonly used to restore the aged bitumen to a condition that resembles that of the virgin bitumen. Three reclaimed asphalt pavement (RAP) stockpiles were sampled, and the aged binders recovered from RAP binders were mixed with recycling agents at ten levels to produce bitumen blends. The blends using virgin bitumen as the softening agent exhibited a significantly different rheological behavior from ones using the rejuvenating agent. The addition of a recycling agent could shift up or down the master curve of the blend vertically, depending on the engineering properties of the recycling agent. A normalized viscosity ratio (NVR) model was used to characterize the rheological properties of aged bitumen mixed with softening and rejuvenating agents. An interaction parameter was introduced into the model to consider the physico-chemical reaction between aged bitumen and recycling agent. This mixing rule was compared to the method specified in the blending chart by the Asphalt Institute (AI). The blending chart was shown to be applicable to determine the amount of the softening agent required to meet the target viscosity. The NVR model appeared to be a better tool for the rejuvenating agent to predict the viscosity of a recovered bitumen blend than the AI chart.

Jian Shiuh Chen

Papers

Asphalt modified by styrene-butadiene-styrene triblock copolymer: Morphology and model

Mechanism and behavior of bitumen strength reinforcement using fibers

Fundamental Characterization of SBS- Modified Asphalt Mixed with Sulfur

Engineering properties and performance of asphalt mixtures incorporating steel slag

Engineering characterization of recycled asphalt concrete and aged bitumen mixed recycling agent