J
John C. Huffman
Researcher at Brandeis University
Publications - 6
Citations - 521
John C. Huffman is an academic researcher from Brandeis University. The author has contributed to research in topics: Steric effects & Peptidomimetic. The author has an hindex of 6, co-authored 6 publications receiving 500 citations. Previous affiliations of John C. Huffman include University of Southern Denmark & Indiana University – Purdue University Indianapolis.
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Journal ArticleDOI
Can terdentate 2,6-bis(1,2,3-triazol-4-yl)pyridines form stable coordination compounds?
TL;DR: The first structurally characterized examples of the 1,2,3-triazole motif employed in a terdentate ligand display enhanced steric freedom and a facile receptivity towards a reversible aquation in the case of an electrogenerated Fe(III) state.
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Remarkably Stable Titanium Complexes Containing Terminal Alkylidene, Phosphinidene, and Imide Functionalities
TL;DR: The Pincer-type complexes of titanium(III) and -(IV) have been shown to be remarkably stable, despite having terminal alkylidene, phosphinidene and imide functionalities.
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Snapshots of an alkylidyne for nitride triple-bond metathesis.
Brad C. Bailey,Alison R. Fout,Hongjun Fan,John E. Tomaszewski,John C. Huffman,J. Brannon Gary,Marc J. A. Johnson,Daniel J. Mindiola +7 more
TL;DR: Isotopic labeling studies applying 15N enriched nitrile N⋮CAd clearly reveal the nitrogen atom transfer results from incomplete and complete metathesis of a titanium alkylidyne with a nitriles.
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Two classes of alongside charge-transfer interactions defined in one [2]catenane.
Sune Nygaard,Stinne Wessel Hansen,John C. Huffman,Frank Jensen,Amar H. Flood,Jan O. Jeppesen +5 more
TL;DR: Molecular modeling studies confirmed that the observed difference in the absorption spectroscopic profile can be accounted for by both a better overlap of the HOMO(TTF) and LUMO+1(CBPQT4+) as well as a more stable face-to-face (pi...pi) conformation in the trans isomer compared to the edge- to-face cis isomer of the [2]catenane.
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Solid-Phase Synthesis of Multiple Classes of Peptidomimetics from Versatile Resin-Bound Aldehyde Intermediates
TL;DR: A wide variety of highly substituted lactam containing peptidomimetic scaffolds are prepared by solid-phase synthesis from a single, versatile class of resin-bound aldehyde intermediates, allowing the construction of a large diversity of substitution patterns for ready use in combinatorial chemistry.