J
Jomon Mathew
Researcher at Technion – Israel Institute of Technology
Publications - 28
Citations - 685
Jomon Mathew is an academic researcher from Technion – Israel Institute of Technology. The author has contributed to research in topics: Chemistry & Ene reaction. The author has an hindex of 15, co-authored 24 publications receiving 592 citations. Previous affiliations of Jomon Mathew include National Institute for Interdisciplinary Science and Technology & National Institute of Advanced Industrial Science and Technology.
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C−H Bond Activation through σ-Bond Metathesis and Agostic Interactions: Deactivation Pathway of a Grubbs Second-Generation Catalyst
TL;DR: In this article, a mechanistic study has been carried out to explore the structural and energetic features leading to the decomposition pathways of a Grubbs second-generation olefin metathesis catalyst using density functional theory.
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Use of molecular electrostatic potential at the carbene carbon as a simple and efficient electronic parameter of N-heterocyclic carbenes.
TL;DR: The MESP topographical approach presented herein offers quantification of the inherent electron donating power of a free N-heterocyclic carbene ligand.
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Quantitative assessment of the stereoelectronic profile of phosphine ligands.
TL;DR: It is found that a two-layer QM-MM ONIOM method comprising PH3 in the inner QM layer and the R groups in the outer MM layer is useful to locate the structure of a PR3 ligand in an electronic effect free environment of the substituents.
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One‐Pot Zinc‐Promoted Asymmetric Alkynylation/Brook‐Type Rearrangement/Ene–Allene Cyclization: Highly Selective Formation of Three New Bonds and Two Stereocenters in Acyclic Systems
Polina Smirnov,Jomon Mathew,Anne Nijs,Einat Katan,Miriam Karni,Carsten Bolm,Yitzhak Apeloig,Ilan Marek +7 more
TL;DR: It's as easy as 1, 2, 3: In a one-pot sequence, two stereocenters and three new bonds were created with high selectivity through an asymmetric alkynylation of acyl silanes, a tandem Brook-type rearrangement and Zn-ene-allene cyclization, the addition of an electrophile, and finally oxidation.
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Engineering fused coumarin dyes: a molecular level understanding of aggregation quenching and tuning electroluminescence via alkyl chain substitution
Sunil Kumar,Punita Singh,Ritu Srivastava,Rik Rani Koner,Avijit Pramanik,Jomon Mathew,Sougata Sinha,Madhu Rawat,R. S. Anand,Subrata Ghosh +9 more
TL;DR: In this article, a series of new coumarin derivatives having a planar structure have been synthesized and characterized, and the effects of systematic variation in alkyl chain functionalization providing morphological variations that permit interesting solid state emitting properties have been discussed simultaneously with electrochemical behavior and OLED (organic light emitting diode) device applications.