J
Joost N. H. Reek
Researcher at University of Amsterdam
Publications - 488
Citations - 23869
Joost N. H. Reek is an academic researcher from University of Amsterdam. The author has contributed to research in topics: Catalysis & Hydroformylation. The author has an hindex of 74, co-authored 458 publications receiving 21217 citations. Previous affiliations of Joost N. H. Reek include Wageningen University and Research Centre & Virginia Tech.
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Synthesis of carbosilane dendritic wedges and their use for the construction of dendritic receptors
TL;DR: In this paper, a divergent route for the synthesis of carbosilane wedges that contain either a bromine or amine as focal point has been developed, which enable the construction of various core-functionalized dendrimers.
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A Novel M8L6 Cubic Cage that Binds Tetrapyridyl Porphyrins; Cage and Solvent Effects in Cobalt-porphyrin-catalyzed Cyclopropanation Reactions.
TL;DR: In this paper, a metal-coordination cage was designed to bind catalytically active porphyrins that is soluble in solvents spanning a wide variety of polarity.
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Control of the overpotential of a [FeFe] hydrogenase mimic by a synthetic second coordination sphere.
TL;DR: Inspired by nature, this work reports a strategy that relies on the selective encapsulation of a synthetic hydrogenase mimic in a novel supramolecular cage that decreases the PRC overpotential by 150 mV and is proposed to originate from the cationic cage stabilizing anionic reaction intermediates within the catalytic cycle.
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Ligand Self‐Sorting and Nonlinear Effects in Dinuclear Asymmetric Hydrogenation: Complexity in Catalysis
TL;DR: NLE is studied in detail using dinuclear hydrogenation catalysts C that have four chiral ligands, which can theoretically be more active and selective than their homochiral analogues.
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Reversible multi-electron storage in dual-site redox-active supramolecular cages.
Raoul Plessius,Nicole Orth,Ivana Ivanović-Burmazović,Maxime A. Siegler,Joost N. H. Reek,Jarl Ivar van der Vlugt +5 more
TL;DR: M6L412+ supramolecular cages 3a and 3b, soluble in organic solvents, contain two different ligand-centered redox sites that enable the reversible storage of up to 16 electrons, as probed by CV, UV/vis spectro-electrochemistry (SEC-UV/Vis), bulk electrolysis and EPR.