Joost N. H. Reek

TL;DR: In this article, a series of DIMPhos ligands with an integral anion binding site (the DIM pocket) is reported, and coordination studies show that these ligands bind to a rhodium center in a bidentate fashion.

TL;DR: The template-induced formation of chelating bidentate ligands by the selective self-assembly of two monodentate pyridyl phosphorus ligands on a rigid bis-zinc(II) salphen template with two identical binding sites was studied and suggested that the rigidity of the template is not an important factor for the improvement of the regio- and enantioselectivity under the applied reaction conditions.

TL;DR: In this article, the synthesis of a series of diphosphine ligands having phosphorus donor atoms in the core of a carbosilane dendrimer and their use in palladium catalysed allylic alkylation is described.

TL;DR: In this paper, the authors present an Uberblick uber die jungsten Fortschritte auf dem Gebiet der Ubergangsmetall-funktionalisierten Dendrimere, die als Katalysatoren eingesetzt werden.

TL;DR: In this paper, the applicability of migratory carbene insertion reactions into TM-C bonds as a new tool for catalytic C-C bond formation is highlighted, with a focus on new developments in palladium mediated cross-coupling reactions and carbene polymerisation.