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Joost N. H. Reek

Researcher at University of Amsterdam

Publications -  488
Citations -  23869

Joost N. H. Reek is an academic researcher from University of Amsterdam. The author has contributed to research in topics: Catalysis & Hydroformylation. The author has an hindex of 74, co-authored 458 publications receiving 21217 citations. Previous affiliations of Joost N. H. Reek include Wageningen University and Research Centre & Virginia Tech.

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Base-free production of H2 by dehydrogenation of formic acid using an iridium-bisMETAMORPhos complex.

TL;DR: An iridium complex based on a cooperative ligand that functions as an internal base is reported that can rapidly and cleanly dehydrogenate formic acid in absence of external base.
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Self-assembly of a confined rhodium catalyst for asymmetric hydroformylation of unfunctionalized internal alkenes

TL;DR: A chiral supramolecular ligand has been assembled and applied to the rhodium-catalyzed asymmetric hydroformylation of unfunctionalized internal alkenes and results in reversed regioselectivity and remarkable enantioselectivities.
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Site-isolation effects in a dendritic nickel catalyst for the oligomerization of ethylene.

TL;DR: In this paper, the dendrimers were used as a ligand design element for the construction of nickel catalysts for ethylene oligomerization, and the results showed that the resulting catalysts outperformed the parent ligand in catalysis in methanol.
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Rh-mediated polymerization of carbenes: mechanism and stereoregulation.

TL;DR: On the basis of a comparison of NMR data with those of known oligomer fragments, the stereochemistry of the new polymer is tentatively assigned as syndiotactic, and observed syndiospecificity is attributed to chain-end control on the rate of N(2) elimination from diastereomeric diazoalkane complexes and/or on the migratory insertion step itself.
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Encapsulated cobalt-porphyrin as a catalyst for size-selective radical-type cyclopropanation reactions.

TL;DR: Interestingly, the M8 L6 encapsulated catalyst reveals size-selectivity, where smaller substrates more easily penetrate through the pores of the "molecular ship-in-a-bottle catalysts" and are hence converted faster than bigger substrates.