J
Joshua J. Stapleton
Researcher at Pennsylvania State University
Publications - 18
Citations - 1629
Joshua J. Stapleton is an academic researcher from Pennsylvania State University. The author has contributed to research in topics: Conductance & X-ray photoelectron spectroscopy. The author has an hindex of 10, co-authored 18 publications receiving 1579 citations.
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Journal ArticleDOI
Conductance Switching in Single Molecules Through Conformational Changes
Zachary J. Donhauser,Brent A. Mantooth,Kevin F. Kelly,Lloyd A. Bumm,Jason D. Monnell,Joshua J. Stapleton,David W. Price,Adam M. Rawlett,David L. Allara,James M. Tour,Paul S. Weiss +10 more
TL;DR: Over time the conductance switching of single and bundled phenylene ethynylene oligomers isolated in matrices of alkanethiolate monolayers is tracked, concluding that the switching is a result of conformational changes in the molecules or bundles, rather than electrostatic effects of charge transfer.
Journal ArticleDOI
Relative Conductances of Alkaneselenolate and Alkanethiolate Monolayers on Au{111}
Jason D. Monnell,Joshua J. Stapleton,Shawn M. Dirk,William A. Reinerth,James M. Tour,David L. Allara,Paul S. Weiss +6 more
TL;DR: Simultaneously acquired apparent tunneling barrier height (ATBH) and scanning tunneling microscopy (STM) images reveal that alkanethiolate molecules have a lower barrier to tunneling, and therefore a higher conductance than alkaneselenolates of the same alkyl chain length.
Journal ArticleDOI
Self-Assembly, Characterization, and Chemical Stability of Isocyanide-Bound Molecular Wire Monolayers on Gold and Palladium Surfaces
Joshua J. Stapleton,Thomas A. Daniel,Sundarajan Uppili,Orlando M. Cabarcos,Jawad Naciri,Ranganathan Shashidhar,David L. Allara +6 more
TL;DR: Self-assembled monolayers of the isocyano derivative of 4,4'-di(phenylene-ethynylene)benzene, a member of the "OPE" family of "molecular wires" of current interest in molecular electronics, have been prepared on smooth, textured films of Au and Pd, showing significant chemical instability when exposed to typical ambient conditions.
Journal ArticleDOI
Ordered Local Domain Structures of Decaneselenolate and Dodecaneselenolate Monolayers on Au{111}
Jason D. Monnell,Joshua J. Stapleton,Jennifer J. Jackiw,T. D. Dunbar,William A. Reinerth,Shawn M. Dirk,James M. Tour,David L. Allara,Paul S. Weiss +8 more
TL;DR: In this paper, a linear missing row structure was found in the (√3 × 3 √3)R30° unit cell of the self-assembled monolayers on Au{111} in high-coverage adsorbate phases.
Journal ArticleDOI
Optical Characterization of Oligo(phenylene−ethynylene) Self-Assembled Monolayers on Gold
Lee J. Richter,Clayton S.-C. Yang,Philip T. Wilson,Philip T. Wilson,Christina A. Hacker,Roger D. van Zee,Joshua J. Stapleton,David L. Allara,Yuxing Yao,James M. Tour +9 more
TL;DR: Vibrationally resonant sum-frequency generation (VR-SFG) and spectroscopic ellipsometry (SE) have been used to characterize self-assembled monolayer films of unsubstituted and mononitro-substitized oligo(phenylene−ethynylene) molecules on vapor-deposited Au substrates as discussed by the authors.