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Kaliyaperumal Thanigaimani

Researcher at Bharathidasan University

Publications -  13
Citations -  161

Kaliyaperumal Thanigaimani is an academic researcher from Bharathidasan University. The author has contributed to research in topics: Hydrogen bond & Ring (chemistry). The author has an hindex of 6, co-authored 13 publications receiving 146 citations. Previous affiliations of Kaliyaperumal Thanigaimani include Fatima College.

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Synthesis, crystal structure, electrochemistry and studies on protein binding, antioxidant and biocidal activities of Ni(II) and Co(II) hydrazone complexes

TL;DR: In this paper, the binding interaction of metal hydrazones with bovine serum albumin (BSA) was studied at normal physiological conditions using fluorescence and UV-Vis spectral techniques.
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Hydrogen-bonded supramolecular motifs in 2-amino-4,6-dimethoxypyrimidinium 4-hydroxybenzoate monohydrate, 2-amino-4,6-dimethoxypyrimidinium 6-carboxypyridine-2-carboxylate monohydrate and 2-amino-4,6-dimethoxypyrimidinium hydrogen (2R,3R)-tartrate 2-amino-4,6-dimethoxypyrimidine.

TL;DR: In the crystal structures of the title compounds, C(6)H(10)N(3)O(2)+.C(7)H (4)NO(4) NO(4)-.H2O, (I), C-H...O hydrogen bonds are observed and the water molecule plays a pivotal role, and five hydrogen-bonded fused rings are formed around the water molecules.
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Hydrogen-bonding patterns in 2-amino-4,6-dimethoxypyrimidinium salicylate

TL;DR: The asymmetric unit of the title compound, C6H10N3O2+·C7H5O3−, contains one 2-amino-4,6-dimethoxy-pyrimidinium cation and a salicylate anion as mentioned in this paper.
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Hydrogen-bonding patterns in 2-amino-4,6-dimethoxy­pyrimidine–4-amino­benzoic acid (1/1)

TL;DR: In the title cocrystal, C6H9N3O2·C7H7NO2, the 2-amino-4,6-dimethoxy­pyrimidine mol­ecule inter­acts with the carboxyl group of the 4-amine­benzoic acid mol­ECule through N—H⋯O and O—H ⋯N hydrogen bonds, forming a cyclic hydrogen-bonded motif.
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Hydrogen-bonded supramolecular motifs in 2-amino-4,6-dimethoxypyrimidinium picrate and pyrimethaminium picrate dimethyl sulfoxide solvate.

TL;DR: Two inversion-related PMN cations are connected through a pair of N-H...N hydrogen bonds involving the 4-amino group and the uncharged N atom of the pyrimidine ring, forming a cyclic hydrogen-bonded R(2)(2)(8) motif.