K
Kerry Gilmore
Researcher at Max Planck Society
Publications - 65
Citations - 4026
Kerry Gilmore is an academic researcher from Max Planck Society. The author has contributed to research in topics: Artemisinin & Singlet oxygen. The author has an hindex of 25, co-authored 64 publications receiving 3023 citations. Previous affiliations of Kerry Gilmore include Free University of Berlin & University of Connecticut.
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The Hitchhiker's Guide to Flow Chemistry
TL;DR: This review introduces readers to the basic principles and fundamentals of flow chemistry and critically discusses recent flow chemistry accounts.
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Cyclizations of Alkynes: Revisiting Baldwin’s Rules for Ring Closure
Kerry Gilmore,Igor V. Alabugin +1 more
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Continuous-Flow Oxidative Cyanation of Primary and Secondary Amines Using Singlet Oxygen
TL;DR: Primary α-aminonitriles were synthesized from the corresponding primary amines for the first time, by an oxidative Strecker reaction at -50 °C, which provides a route to racemic amino acids, which was exemplified by the synthesis of tert-leucine hydrochloride from neopentylamine.
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Rules for anionic and radical ring closure of alkynes.
TL;DR: This work reexamined the stereoelectronic basis for the "favored attack trajectories" regarding the nucleophilic and radical cyclizations of alkynes by dissection of the activation barrier into the intrinsic barrier and thermodynamic component via Marcus theory.
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Finding the right path: Baldwin “Rules for Ring Closure” and stereoelectronic control of cyclizations
Igor V. Alabugin,Kerry Gilmore +1 more
TL;DR: The rules for ring closure formulated by Sir Jack Baldwin in 1976 constitute one of such bold intellectual advances that have become the common starting point in the design of new cyclization reactions and catalyzed the development of modern stereoelectronic concepts.