L
L. M. Abdrakhmanova
Researcher at Russian Academy of Sciences
Publications - 33
Citations - 175
L. M. Abdrakhmanova is an academic researcher from Russian Academy of Sciences. The author has contributed to research in topics: Hexafluoroacetone & Chloral. The author has an hindex of 8, co-authored 33 publications receiving 164 citations.
Papers
More filters
Journal ArticleDOI
A new approach to the synthesis of phosphoranes based on the reaction of benzo[d]-1,3,2-dioxaphospholes having a β- or γ-carbonyl group in exocyclic substituent with hexafluoroacetone
L. M. Abdrakhmanova,Vladimir F. Mironov,T. A. Baronova,Mudaris N. Dimukhametov,Dmitry B. Krivolapov,Igor A. Litvinov,A. A. Balandina,Shamil K. Latypov,Alexander I. Konovalov +8 more
TL;DR: The reaction of 2-(2-oxo-1,2-diphenylethoxy)-and 2-(1-methyl-3-oxobut-2-en-1-yloxy)benzo[d]-1,3,2dioxaphospholes with hexafluoroacetone is a versatile approach to the synthesis of 6,6-bis(trifluoromethyl)-3,4-dipsyl-1.1]heptane and 3,5-dimethyl-7,7-bis
Journal ArticleDOI
The Molecular Design of “Carcass”-Type Phosphoranes, Based on the Reaction of P(III)-Cyclic Derivatives and Unsaturated Activated Compounds
L. M. Abdrakhmanova,V. F. Мironov,Tatyana Gryaznova,Sergey A. Katsyuba,Mudaris N. Dimukhametov +4 more
TL;DR: In this article, a methodology for the synthesis of carcass-type (cage-like type) phosphoranes was developed, which allows us to obtain the products of the given structure with a high regio- and stereoselectivity in the result of cascade processes.
Journal ArticleDOI
Synthesis of spirophosphoranes containing a phosphorus–carbon bond using the reactions of substituted benzo[d]-1,3,2-dioxaphospholes with diethyl acetylenedicarboxylate
L. M. Abdrakhmanova,Vladimir F. Mironov,T. A. Baronova,Mudaris N. Dimukhametov,Dmitry B. Krivolapov,Igor A. Litvinov,Rashid Z. Musin,Alexander I. Konovalov +7 more
TL;DR: The reaction of 2-(2-oxo-1,2-diphenyl)ethoxy- and 2-( 2-methyl carbonyl)phenyloxybenzo[d]-1,3,2dioxaphospholes with diethyl acetylenedicarboxylate was used to synthesise 5,6-bis(ethoxycarbonyl)-3,4-dimethyl-1-phospha-2,8-dioxabicyclo-[3.2.11,5]oct-6-ene in
Journal ArticleDOI
The 3‐Acetyloxaphosphirane/1,3,2‐Dioxaphosphol‐4‐ene Rearrangement
TL;DR: In this paper, a pericyclic shift of the phosphorus fragment in an oxaphosphirane complex was proposed, which is slightly unfavored (ΔΔE = 2.2 kcal/mol) and involves heterolytic P-C bond cleavage.
Journal ArticleDOI
Synthesis of new spirophosphoranes bearing the phosphorus–carbon bond by cascade reactions of 2-(2-methyl-4-oxopent-2-yloxy)benzo- 1,3,2-dioxaphosphole with activated carbonyl compounds
L. M. Abdrakhmanova,Vladimir F. Mironov,Mudaris N. Dimukhametov,Dmitry B. Krivolapov,Igor A. Litvinov +4 more
TL;DR: Cascade reactions of 2-(2-methyl-4-oxopent-2-yloxy)benzo-σ3λ3-1,3,2-dioxaphosphole with chloral, hexafluoroacetone, mezoxalic acid diethyl ester and trifluoropyruvic acid ethyl esters are a versatile approach to the synthesis of spirophosphoranes bearing a phosphorus-carbon bond with a high yield and stereoselectivity as mentioned in this paper.