We present a subpicosecond time resolved polarization selective transient grating (TG) investigation of pentylcyanobiphenyl (5CB) in its isotropic liquid phase. This system shows complex molecular dynamics with various contributions to the TG signal. With an excitation wavelength λexc=665 nm one induces an anisotropy in the sample from the electronic and nuclear Kerr effects. Exciting with λexc=575 nm generates an excited state grating because of two photon absorption. Solvent relaxation around the excited molecule on a few ps time scale is observed because it spectrally shifts the excited state–excited state transition which is monitored by the TG signal. In addition, radiationless relaxation leads to local heating of the sample in a spatial pattern which mimics the optical interference pattern which established the TG. The heating generates an acoustic standing wave. It is demonstrated that with a single TG setup, polarization selection allows separation and identification of all of the above‐mentioned ...

Analysis of complex molecular dynamics in an organic liquid by polarization selective subpicosecond transient grating experiments

Poursuivant la realisation de methodes de caracterisation d'un fluide en ecoulement par diffusion Rayleigh forcee, nous avons mis au point une technique de marquage d'une figure bidimensionnelle quelconque dans le fluide par imagerie optique. L'impression de ce reseau et la visualisation directe de sa deformation permettent d'obtenir une mesure directe des composantes du gradient de vitesse.

https://hal.archives-ouvertes.fr/jpa-00244976/document

Nouvelle technique de marquage d'écoulement par utilisation de molécules photochromes

In forced Rayleigh scattering of mixtures or suspensions the temperature gratings generate, by the Soret effect, concentration gratings that may be very important since they produce both a phase and an amplitude grating superimposed on the principal one. The experimental evidence of their influence was given by Thyagarajan and Lallemand using a mixture of carbondisulfide and ethanol. In this paper we study the temporal behaviour of the concentration grating versus the sample properties and its effect on the detected diffracted beam. Explicit expressions are given for the output intensity taking into account both the generated amplitude and phase gratings.

Soret effect in forced Rayleigh scattering

2014 We present a new visualization technique of an hydrodynamic flow using a thermal grid, « written » in the liquid by means of a pulsed laser, and whose image is subsequently formed, using standard optics, by illumination by a continuous laser. The experiment gives access to a new Doppler-anemometric technique which does not involve the presence of particles in the fluid and to an instantaneous image of a finite volume of the flow. J. Physique LETTRES 41 (1980) L-519 L-521 1 Classification Physics Abstracts 47.80 1 er NOVEMBRE 1980. The instantaneous visualization and velocity measurement of a finite domain of flow is of considerable interest for unsteady or turbulent velocity field u(r, t). Several methods are based on the periodic injection Fig. 1. In the Poiseuille flow cell (C) a thermal grating G is formed at initial time (t = 0) by the interference of two beams coming from a pulsed Nd YAG laser Lp. The second laser La illuminates this grid and is diffracted (orders 0, 1, 1). The Doppler shifted signals 1, 1 can be used to set an anemometric measurement by standard heterodyne technique. Another possibility is the formation of an image of the grid in the plane I conjugate of G through the lens L. If the laser La is switched on (by means of an acoustooptic modulator) for a short time period (t, t + At), the image reflects the integrated effect of the flow field between t = 0 and t. of lines of lagrangian markers (dye, solid particles, bubbles) in the fluid [1]. The lines distort as they move with the flow, due to the velocity gradients; a measurement of the integrated displacement and of u(r, t) is possible as long as the diffusion has not washed away the lines. The letter discusses a related technique in which a thermal grid is « written » in a very short time (tp 10 ns) within a liquid using the pattern formed by the interference of two beams from a pulsed laser Lp [2] (Fig. 1). In a previous paper [3] we have shown some applications of the forced Rayleigh technique [4] to hydrodynamics : if the thermal grid is « read » by a second laser La (cw HeNe 10 mW) incident at right angle with the wave vector of the index grating formed by the thermal grid, the exponential time decay of the intensity of the diffracted peaks gives access to the thermal diffusivity in the flow (Fig. 2a) as in static experiments. Moreover, the rotation and distortion of the grid caused by the velocity gradients are measured through the corresponding changes of the diffraction pattern. The average velocity u (in the grid volume) is automatically subtracted by the diffraction process; this is of particular interest for the study of the structure of turbulence which is determined in terms of the gradient components. Moreover, this experiment gives an average information over the size of the laser La. Article published online by EDP Sciences and available at http://dx.doi.org/10.1051/jphyslet:019800041021051900 L-520 JOURNAL DE PHYSIQUE LETTRES Fig. 2. a) Classical decay of a forced Rayleigh signal : intensity of the first diffracted order (with an exponential time constant T = p2/(8 ~2 K) where p is the wavelength of the grid, K the thermal diffusivity). b) The output signal Ia of a photodetector placed in the image of the grid : a periodic modulation is superimposed to the exponential decay with a frequency 2 Av proportional to u. The present extension of the technique is quite complementary : i) it permits to observe the thermal grid not only in the Fourier space but also in real space; thus it has spatial resolution; ii) it can give a measure of u which, in the forced Rayleigh experiment, was « memorized » as a Doppler shift of the frequency of the diffracted order ± 1 as Av = plii [1] (where p = period of the thermal grid). The information in u can be extracted by mixing the diffracted beams ± 1. This is the principle of the experiment sketched in the right part of figure 1 : the two beams ± 1 are recombined to form the image of the grid in a plane I, conjugate of the index grating, through the lens L (the image is magnified by a ratio m = q’/q ’\" 10). In the focal plane of L, the screen S acts as an aperture stop in the Fourier space and suppresses the central beam. The strioscopic technique gives an image (amplitude grating) of 100 % contrast. The motion of the image at a velocity mu(r, t) follows that of the object grid. The photographs (Fig. 3) shows a sequence of two images of a flow. The grid is initially (time t = 0) perpendicular to the plates of a plane Poiseuille flow cell (the flow being uniform along the direction y of the laser La). At a subsequent time (t = 300 ~s), the parabolic velocity profile of the laminar flow is seen from the integrated motion of the grid. Fig. 3. Photographs of the grid in the image plane I at two different times : a) t = 0 : right when the grid was formed in the flow cell; b) t = 300 us : grid convected by the Poiseuille flow. We also notice the decay of intensity due to thermal diffusion between the photographs taken with equal exposure time At = 20 us. One can extend the technique to non uniform Poiseuille flows and suppress the integration along the y direction by replacing the spherical lens used to form the index grating by a cylindrical one. In particular for the visualization of small turbulent structures [5] the thickness of the vertical « ribbon » of pulsed laser light should be kept comparable to the Kolmogorov scale. The present experiment is limited by the sensitivity of the recording film [6]. In order to avoid fuzzy images, the exposure time has to be kept of the order of T/I0, where the period of displacement of the grid is T ~ 10-4 s for a grating of period p ~ 100 Ilm and u ~ 1 m/s. The limit is quite severe for turbulent flows where the attenuation of the grid intensity by turbulent diffusion can be much faster than in laminar flows. It is also possible to place a small (of extent p’/2 where p’ is the period of the image grid) photodetector in a prescribed point of the image flow field. The variaL-521 AN ANEMOMETRIC AND FLOW VISUALIZATION TECHNIQUE tion of intensity with time is given in the figure 2b. In addition to exponential diffusive decay, the periodic modulation at a frequency 2 Av (given by [1]) is a measure of the local velocity u(r) during the lifetime of the grid. This laser Doppler anemometry technique is complementary to the classical LDA one [7] : in the latter case, particles move within the flow through a fixed grid ; in the present experiment, the grid moves as a whole through the reference line of the La beam. Our experiment is not a true lagrangian one because different parts of the grid pass through the laser beam. However, it offers several advantages : i) it does not require the presence of tracer particles in the flow ; ii) it allows the simultaneous measurement of the diffusivity and of one velocity component. Such a joint information can be of interest in particular in the study of two-dimensional turbulent flow fields where it is known that the turbulent mixing can be controled by the large eddy structures [8] ; iii) measurement of the velocity in different points of the flow field can be done simultaneously or sequentially by using several small detectors in the image plane I. Let us finally note that a simpler LDA measurement can be obtained by mixing one of the diffracted beams with unshifted diffused light from the central beam. However in this case we lose the dual information on the map of velocity field obtained by means of the grid image.

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A non-perturbative anemometric and flow visualization technique

A method of measuring velocity gradients on the basis of a photon correlation technique has been developed. Depending on the scattering geometry, particular rows of the velocity gradient tensor Gamma can be determined for laminar flow without any knowledge of the flow symmetry. The method is also applicable to turbulent flow. With the assumption of a normal distribution of the tensor elements of one row of Gamma , the measured correlation functions for a tube flow can be fitted satisfactorily. Limits of the applicability of the method are discussed.

https://iopscience.iop.org/article/10.1088/0022-3727/21/2/002/pdf

The measurement of velocity gradients in laminar and turbulent flow

We describe an experiment which allows the measurement of transverse velocity gradients and laminar and turbulent diffusion. A pulsed laser instantaneously ’’writes’’ a phase grating in a flowing liquid, and is subsequently ’’read’’ by forming its diffraction image with a second laser. Results are presented both in the laminar and turbulent regime for a plane Poiseuille flow.

A direct optical measurement of velocity gradients

We applied the forced Rayleigh scattering technique to study laminar and turbulent flows. We recorded the optical Fourier transform of a transient grating created in a flowing liquid. Depending on the type of detection used, FRS provides either a direct measurement of velocity gradients or the determination of an effective turbulent diffusivity. Experimental results in a plane Poiseuille flow are given.

L. Petit

Papers

A direct optical measurement of velocity gradients

Application of forced Rayleigh scattering to hydrodynamic measurements