Long Lu

TL;DR: The authors gratefully acknowledge financial support from theNational Basic Research Program of China (2012CB821600, 2010CB126103), the Key Program of Natural Science Foundation ofChina (21032006), the National Natural Science foundation ofChina, Agro-scientific Research inthe Public Interest, the National Key TechnologiesR&D Program (2011BAE06B05), the Shanghai Scientific ResearchProgram (10XD1405200), and SIOC for financial support.

TL;DR: Two different types of electrophilic trifluoromethylthiolating reagents are discovered, which are more reliable in transition-metal-Catalyzed reactions such as copper-catalyzed trif LU/vinyl/alkylboronic acids and silver-catalystzed decarboxylative trifLUorometHylthio group into small molecules and aliphatic carboxylic acids as well as in the organocatalytic asymmetric

TL;DR: AlA has promotive effects in the recovery of growth and development of rape seedlings under herbicide ZJ0273 toxicity stress, and it is found that plants treated with 1 mg/L ALA produced the highest shoot fresh weights, shoot lengths, rootfresh weights, and root oxidizability when the seeds were treated with different concentrations of ZJ 0273.

TL;DR: It was proposed that the radical, generated from the silver-catalyzed decarboxylation in the "oil-in-water" droplets, could easily react with the trifluoromethylthiolating reagent to form the product.

TL;DR: The super electrophilicity of a shelf-stable, easily prepared trifluoromethylthio-dibenzenesulfonimide 7 was demonstrated and exhibits reactivity remarkably higher than that of other known electrophilic trifLUorometHylthiolating reagents.