L
Luigi Toniolo
Researcher at Ca' Foscari University of Venice
Publications - 144
Citations - 2709
Luigi Toniolo is an academic researcher from Ca' Foscari University of Venice. The author has contributed to research in topics: Catalysis & Palladium. The author has an hindex of 28, co-authored 144 publications receiving 2598 citations. Previous affiliations of Luigi Toniolo include Brown University & National Chemical Laboratory.
Papers
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Journal ArticleDOI
Interplay between Nitrogen Concentration, Structure, Morphology, and Electrochemical Performance of PdCoNi “Core–Shell” Carbon Nitride Electrocatalysts for the Oxygen Reduction Reaction
Enrico Negro,Keti Vezzù,Federico Bertasi,Piero Schiavuta,Luigi Toniolo,Stefano Polizzi,Vito Di Noto +6 more
TL;DR: In this paper, the performance of a core-shell electrocatalyst for proton exchange membrane fuel cells (PEMFCs) was investigated using high-resolution transmission electron microscopy (HR-TEM).
Journal ArticleDOI
On the mechanism of the hydrocarbalkoxylation of olefins catalyzed by palladium complexes
Gianni Cavinato,Luigi Toniolo +1 more
TL;DR: In this article, the acyl complex PdCl(COR)(PPh3)2 (R = Et, n-Hex), isolated during the course of hydro-carbalkoxylation reactions catalyzed by the precursor system PdCL2(PPh 3)2-PPh4 (95°C, P(CO) 100-120 atm; Pd: P = 1:3-4), in ethanol or higher alkanols as solvents, reacts with an alkanol R'OH in the presence of added P
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On the mechanism of hydroesterification of styrene using an in situ-formed cationic palladium complex
TL;DR: In this paper, the mechanism of hydroesterification of styrene using in situ-formed Pd(OTs) 2 (PPh 3 ) 2 from PdOAc) 2, PPh 3 and TsOH in methanol has been investigated by isolation and characterisation of catalytically active intermediates.
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Synthesis, studies and fuel cell performance of “core–shell” electrocatalysts for oxygen reduction reaction based on a PtNix carbon nitride “shell” and a pyrolyzed polyketone nanoball “core”
TL;DR: In this article, a new class of "core-shell" electrocatalysts for oxygen reduction reaction (ORR) processes for application in Proton Exchange Membrane Fuel Cells (PEMFCs) is described.
Journal ArticleDOI
Carbon monoxide-ethylene copolymerization catalyzed by a Pd(AcO)2/dppp/TsOH system: the promoting effect of water and of the acid
Andrea Vavasori,Luigi Toniolo +1 more
TL;DR: In the case of copolymerization, it was shown in this article that the catalytic cycle is initiated by the insertion of carbon monoxide with water on the metal center, via a reaction closely related to the water gas shift reaction.