L
Luigi Toniolo
Researcher at Ca' Foscari University of Venice
Publications - 144
Citations - 2709
Luigi Toniolo is an academic researcher from Ca' Foscari University of Venice. The author has contributed to research in topics: Catalysis & Palladium. The author has an hindex of 28, co-authored 144 publications receiving 2598 citations. Previous affiliations of Luigi Toniolo include Brown University & National Chemical Laboratory.
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Synthesis, characterization and fluxional behaviour of allylic palladium(II) carboxylate and N,N′- diarylformamidido complexes
TL;DR: In this paper, it was shown that the presence of weak bridge-splitting ligands, such as DMSO or the parent N,N′ -diarylformamidine, does not affect the intramolecular process, which occurs without any palladium-formamidido bond breaking, probably through a boat inversion of the C 2 N 4 Pd 2 ring via a chair conformation.
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Allylic palladium(II) triazenido complexes: synthesis and spectroscopic studies
TL;DR: In this article, the reaction of [Pd(1-3-η-allyl)Cl]2 with lithium triazenide (triazenides = p-XC6H4NN-NC 6H4X-p; X = Cl, H, CH3) with 1H NMR spectra demonstrate the presence of two conformers in solution.
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Copolymerization of ethylene and carbon monoxide using [(dppp)Pd(H2O)(TsO)](TsO) as a catalyst precursor: rate equation
TL;DR: In this article, the influence of CO and C2H4 pressures on copolymerization catalyzed by the precursor [(dppp)Pd(H2O)(TsO)](TsO) in MeOH has been studied up to 8 Mpa of total pressure at 363 K. Several rate equations, based on two different models, are presented.
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Hydroxylamine production via hydrogenation of nitric oxide in aqueous sulfuric acid catalyzed by carbon-supported platinum
Stefano Polizzi,Alvise Benedetti,Giuliano Fagherazzi,C. Goatin,R. Strozzi,G. Talamini,Luigi Toniolo +6 more
TL;DR: In this article, a study of the hydrogenation of nitric oxide to hydroxylamine in aqueous sulfuric acid in the presence of platinum supported on high-surface-area active carbon as catalyst is presented.
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Influence of the reaction conditions on the productivity and on the molecular weight of the polyketone obtained by the CO-ethene copolymerisation catalysed by [Pd (TsO) (H2O) (dppp)](TsO) in MeOH
TL;DR: In this paper, the influence of operating conditions on the productivity on the CO-ethene copolymerisation catalysed by the title complex used in combination with TsOH and on the average numerical molecular weight was studied.