L
Luis F. Veiros
Researcher at Instituto Superior Técnico
Publications - 256
Citations - 7415
Luis F. Veiros is an academic researcher from Instituto Superior Técnico. The author has contributed to research in topics: Catalysis & Ligand. The author has an hindex of 45, co-authored 251 publications receiving 6467 citations. Previous affiliations of Luis F. Veiros include Technische Universität München & Vienna University of Technology.
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Journal ArticleDOI
Divergent Coupling of Alcohols and Amines Catalyzed by Isoelectronic Hydride MnI and FeII PNP Pincer Complexes
Matthias Mastalir,Mathias Glatz,Nikolaus Gorgas,Berthold Stöger,Ernst Pittenauer,Günter Allmaier,Luis F. Veiros,Karl Kirchner +7 more
TL;DR: An efficient coupling of alcohols and amines catalyzed by well-defined isoelectronic hydride Mn(I) and Fe(II) complexes, which are stabilized by a PNP ligand based on the 2,6-diaminopyridine scaffold, which is an environmentally benign process implementing inexpensive, earth-abundant non-precious metal catalysts.
Journal ArticleDOI
Mechanism for the cyclotrimerization of alkynes and related reactions catalyzed by CpRuCl.
TL;DR: A complete catalytic cycle for the cyclotrimerization of acetylene with the CpRuCl fragment has been proposed and discussed based on DFT/B3LYP calculations, which revealed a couple of uncommon intermediates.
Journal ArticleDOI
Iminoboronates: A New Strategy for Reversible Protein Modification
Pedro M. S. D. Cal,João B. Vicente,Elisabete Pires,Ana Varela Coelho,Luis F. Veiros,Carlos Cordeiro,Pedro M. P. Gois +6 more
TL;DR: A new strategy to modify the lysine's ε-amino group and the protein's N-terminal, based on the formation of stable iminoboronates in aqueous media, enables the stable and complete modification of these amine groups.
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The nature of the indenyl effect
TL;DR: The study of the folding of free Cp and Ind, combined with the (eta(5/3)-Cp')-M bond analysis, shows that the observed difference is not the result of an intrinsic characteristic of the indenyl ligand, such as the traditionally accepted aromaticity gain in the benzene ring formed in eta(3)-Ind complexes.
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Stable, Yet Highly Reactive Nonclassical Iron(II) Polyhydride Pincer Complexes: Z-Selective Dimerization and Hydroboration of Terminal Alkynes.
TL;DR: The synthesis, characterization, and catalytic activity of nonclassical iron(II) polyhydride complexes containing tridentate PNP pincer-type ligands is described and they efficiently promote the catalytic dimerization of aryl acetylenes giving the corresponding conjugated 1,3-enynes in excellent yields with low catalyst loadings.