 Many atmospheric chemicals occur in the gas phase as well as in liquid cloud droplets and aerosol particles Therefore, it is necessary to understand the distribution between the phases According to Henry's law, the equilibrium ratio between the abundances in the gas phase and in the aqueous phase is constant for a dilute solution Henry's law constants of trace gases of potential importance in environmental chemistry have been collected and converted into a uniform format The compilation contains 17 350 values of Henry's law constants for 4632 species, collected from 689 references It is also available at http://wwwhenrys-laworg 

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Compilation of Henry's law constants (version 4.0) for water as solvent

Carbon dioxide is often promoted as a sustainable solvent, as CO 2 is non-flammable, exhibits a relatively low toxicity and is naturally abundant. However, injudicious use of carbon dioxide in a process or product can reduce rather than enhance overall sustainability. This review specifically examines the use of CO 2 to create greener processes and products, with a focus on research and commercialization efforts performed since 1995. The literature reveals that use of CO 2 has permeated almost all facets of the chemical industry and that careful application of CO 2 technology can result in products (and processes) that are cleaner, less expensive and of higher quality.

Supercritical and near-critical CO2 in green chemical synthesis and processing

Henry gas solubility optimization: A novel physics-based algorithm

The development of van der Waals cubic equations of state and their application to the correlation and prediction of phase equilibrium properties is presented and analyzed. The discussion starts with a brief account of the contributions to equation of state development during the years before van der Waals. Then, the original equation proposed in the celebrated thesis of van der Waals in 1873 and its tremendous importance in describing fluid behavior are analyzed. A chronological critical walk through the most important contributions during the first part of the 1900s is made, to arrive at the proposal that I consider to be the most outstanding since van der Waals:  the equation proposed by Redlich and Kwong in 1949. The contributions after Redlich and Kwong to the modern development of equations of state and the most recent equations proposed in the literature are analyzed. The application of cubic equations of state to mixtures and the development of mixing rules is put in a proper perspective, and the ...

The state of the cubic equations of state

Application of gas hydrate formation in separation processes: A review of experimental studies

Economic evaluation of natural gas hydrate as an alternative for natural gas transportation

Energy consumption and economic evaluation of water desalination by hydrate phenomenon

A simplified method for calculating saturated liquid densities

Prediction of equilibrium conditions for gas hydrate formation in the mixtures of both electrolytes and alcohol

This paper is a comparative study of 15 cubic equations of state (EoSs) for predicting natural gas dew points. Two-, three-, and four-parameter EoSs are used to predict the natural gas dew points. Natural gases contain a large amount of supercritical methane; therefore, the fugacity of methane, as a test of suitability of the EoSs, is predicted and compared to the recommended values in International Union of Pure and Applied Chemistry (IUPAC) tables. The vapor pressures of components that are normally present in natural gas mixtures, as another test of the suitability of the EoSs, are also predicted and compared with experimental data. The dew points of several natural gas mixtures then are predicted, using the EoSs, and compared to experimental values. Results reveal that the dew points of lean synthetic natural gases are predicted best by the Redlich-Kwong family of EoSs, whereas rich natural gases dew points are described significantly better by the Patel-Teja family of EoSs.

Mahmood Moshfeghian

Papers

Economic evaluation of natural gas hydrate as an alternative for natural gas transportation

Energy consumption and economic evaluation of water desalination by hydrate phenomenon

A simplified method for calculating saturated liquid densities

Prediction of equilibrium conditions for gas hydrate formation in the mixtures of both electrolytes and alcohol

Predicting Natural Gas Dew Points from 15 Equations of State