M
Manja Grosche
Researcher at Technische Universität München
Publications - 19
Citations - 1548
Manja Grosche is an academic researcher from Technische Universität München. The author has contributed to research in topics: Catalysis & Palladium. The author has an hindex of 12, co-authored 19 publications receiving 1524 citations. Previous affiliations of Manja Grosche include Chemnitz University of Technology & Nanyang Technological University.
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A defined N-heterocyclic carbene complex for the palladium-catalyzed Suzuki cross-coupling of aryl chlorides at ambient temperatures.
Christian W. K. Gstöttmayr,Volker P. W. Böhm,Eberhardt Herdtweck,Manja Grosche,Wolfgang A. Herrmann +4 more
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Polymer-Supported Carbene Complexes of Palladium: Well-Defined, Air-Stable, Recyclable Catalysts for the Heck Reaction
Jürgen Schwarz,Volker P. W. Böhm,Michael G. Gardiner,Manja Grosche,Wolfgang A. Herrmann,Wolfgang Hieringer,Gabriele Raudaschl-Sieber +6 more
TL;DR: N-Heterocyclic dicarbene chelate complexes efficiently catalyze the Heck reaction of activated and non-activated arylbromides, are recyclable under aerobic conditions and exhibit hardly any leaching, which is in line with theoretical investigations on ligand dissociation energies related to Pd0 and PdII centres.
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Synthesis, structure and catalytic application of palladium(II) complexes bearing N-heterocyclic carbenes and phosphines
Wolfgang A. Herrmann,Volker P. W. Böhm,Christian W. K. Gstöttmayr,Manja Grosche,Claus-Peter Reisinger,Thomas Weskamp +5 more
TL;DR: A variety of mixed palladium(II) complexes bearing N-heterocyclic carbenes (NHCs) and triaryl-and trialkylphosphines [NHC(R2)]Pd(PR′3)I2 (R=Me, t-Bu, (R)-1-phenylethyl; R′=Ph, o-tolyl, cyclohexyl, T-Bu) have been prepared.
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Developing Transition-Metal Catalysts for the Intramolecular Hydroamination of Alkynes
Thomas Müller,Manja Grosche,Eberhardt Herdtweck,‡ Anna-Katharina Pleier,and Erik Walter,Yaw Kai Yan +5 more
TL;DR: The catalytic properties of the transition-metal complexes depend on the appropriate choice of ligand, solvent, temperature, and counteranion as mentioned in this paper, and the X-ray crystal structure of one catalyst, [PdCl(triphos)](CF3SO3).
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Unsymmetrically Substituted Iridium(III)−Carbene Complexes by a CH-Activation Process†
TL;DR: In this paper, the metalhydride Cp*(L ǫ)IrH+OTf was synthesized by a cyclohexane-to-cyclohexene transformation at the N-hete.