Manuel Martínez

TL;DR: In this paper, a novel approach mixing the qualities of hard-modeling and soft-modelling methods is proposed to analyse kinetic data monitored spectrometrically, taking as a basis the Multivariate Curve Resolution-Alternating Least Squares method (MCR-ALS), which obtains the pure concentration profiles and spectra of all absorbing species present in the raw measurements by using typical softmodeling constraints, a new hard constraint is introduced to force some or all the concentration profiles to fulfill a kinetic model, which is refined at each iterative cycle of the optimisation process

TL;DR: The cyclometalation reactions of benzylidenebenzylamines, -anilines, and -propylamine with palladium acetate have been studied in toluene solution as mentioned in this paper.

TL;DR: The binding of CO in these rhodium complexes was found to be fully reversible, and release studies of carbon monoxide via thermogravimetric measurements have also been carried out.

TL;DR: In this article, the reactivity, synthetic and structural chemistry, as well as some physical and chemical properties of a series of discrete dinuclear mixed-valence cyano-bridged complexes of general formulae [LnCoIII(mu NC)Fe-II(CN)(5)](-) (L = pentadentate macrocyclic ligand) are reviewed.