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Xavier Solans
Researcher at University of Barcelona
Publications - 582
Citations - 14129
Xavier Solans is an academic researcher from University of Barcelona. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 55, co-authored 582 publications receiving 13812 citations. Previous affiliations of Xavier Solans include University of Valencia.
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Journal ArticleDOI
Unique Single-Atom Binding of Pseudohalogeno Ligands to Four Metal Ions Induced by Their Trapping into High-Nuclearity Cages
Giannis S. Papaefstathiou,Spyros P. Perlepes,Albert Escuer,Ramon Vicente,Mercè Font-Bardia,Xavier Solans +5 more
TL;DR: μ4 end-on coordination (through the N atom) of the pseudohalogeno ligands X- =N3- and NCO- has been observed in the isostructural nonanuclear CoII cages with the general formula.
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Crystal structure and magnetic interactions in nickel(II) dibridged complexes formed by two azide groups or by both phenolate oxygen-azide, -thiocyanate, -carboxylate, or -cyanate groups.
Subrata Kumar Dey,Nijhuma Mondal,M. Salah El Fallah,Ramon Vicente,Albert Escuer,Xavier Solans,Mercè Font-Bardia,T. Matsushita,V. Gramlich,Samiran Mitra +9 more
TL;DR: Tridentate/tetradentate Schiff base ligands L(1) and L(2), derived from the condensation of o-vanillin or pyridine-2-aldehyde with N,N-dimethylethylenediammine, react with nickel acetate or perchlorate salt and azide, cyanate, or thiocyanate to give rise to a series of dinuclear complexes.
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Structure of the linear trinuclear complex hexakis(acetato)bis(2,2'-bipyridine)trimanganese (II). Determination of the J electron-exchange parameter through magnetic susceptibility and high-field magnetization measurements
S. Menage,S. E. Vitols,Pierre Bergerat,Epiphane Codjovi,Olivier Kahn,Jean-Jacques Girerd,Maurice Guillot,Xavier Solans,T. Calvet +8 more
TL;DR: The trinuclear cluster Mn II 3 (CH 3 CO 2 ) 6 (bpy) 2 has been synthesized and its crystal structure was determined in this paper, and it crystallizes in the triclinic system, space group P1, with a=12.849, b=9.790, c=8.187, α=108.50, β=96.41, and V=912.5
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Reactivity in polynuclear transition metal chemistry as a means to obtain high-spin molecules: substitution of μ4-OH− by η1,μ4-N3− increases nine times the ground-state S value of a nonanuclear nickel(II) cage
Giannis S. Papaefstathiou,Albert Escuer,Ramon Vicente,Mercè Font-Bardia,Xavier Solans,Spyros P. Perlepes +5 more
TL;DR: The reaction of di-2-pyridyl ketone, (2-py)2CO, with Ni(O2CMe)(2).4H2O yields the cage that contains extremely rare eta 1,mu 4-N3- groups; magnetic studies reveal that the spin ground state of the latter is nine times the groundState of the former.