M
Martin Gazvoda
Researcher at University of Ljubljana
Publications - 34
Citations - 572
Martin Gazvoda is an academic researcher from University of Ljubljana. The author has contributed to research in topics: Catalysis & Reagent. The author has an hindex of 11, co-authored 29 publications receiving 436 citations.
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Journal ArticleDOI
Mechanism of copper-free Sonogashira reaction operates through palladium-palladium transmetallation
TL;DR: Experimental and theoretical support is provided for two interlinked palladium cycles operating in the debated Sonogashira coupling mechanism.
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Exploring the Scope of Pyridyl- and Picolyl-Functionalized 1,2,3-Triazol-5-ylidenes in Bidentate Coordination to Ruthenium(II) Cymene Chloride Complexes
Aljoša Bolje,Stephan Hohloch,Damijana Urankar,Andrej Pevec,Martin Gazvoda,Biprajit Sarkar,Janez Košmrlj +6 more
TL;DR: In this paper, N-heterocyclic carbene precursors for bidentate coordination to ruthenium(II) through the CNHC and Npyridyl donors were investigated.
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Advances and mechanistic insight on the catalytic Mitsunobu reaction using recyclable azo reagents.
TL;DR: Catalytic Mitsunobu reactions have been substantially improved based on strict optimization, mechanistic studies and discovery of a new catalyst.
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A mesoionic bis(Py-tzNHC) palladium(II) complex catalyses “green” Sonogashira reaction through an unprecedented mechanism
Martin Gazvoda,Miha Virant,Andrej Pevec,Damijana Urankar,Aljoša Bolje,Marijan Kočevar,Janez Košmrlj +6 more
TL;DR: A novel bis(pyridyl-functionalized 1,2,3-triazol-5-ylidene)-palladium(II) complex catalyses the copper-, amine-, phosphine-, and additive-free aerobic Sonogashira alkynylation of (hetero)aryl bromides in water as the only reaction solvent.
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The "Fully Catalytic System" in Mitsunobu Reaction Has Not Been Realized Yet.
TL;DR: An investigation of the recently reported "fully catalytic Mitsunobu reaction" using catalytic amounts of a phosphine reagent and an azo reagent has shown that although benzyl 4-nitrobenzoate is formed under the fully catalytic conditions, the same result is obtained if the hydrazine catalyst is omitted, indicating that this is not a MitsunOBu reaction.