Martin Gazvoda

TL;DR: An unprecedented reactivity of 3-aminoquinoline-2, 4-diones is reported and a proposed mechanism of the rearrangement and the conformational equilibrium of 1,4-benzodiazepine- 2,5-dione rings are discussed.

TL;DR: A copper-catalyzed cycloaddition of hydrogen azide with terminal alkynes to form 4-substituted-1H-1,2,3-triazoles in a sustainable manner is reported, showing diverse functional group tolerance and applicable for late-stage functionalization synthetic strategies.

TL;DR: SC-DSC analysis of representative 2-arylazocarboxylate and 2- Daryl azocar boxamide derivatives has shown high thermal stability, indicating that these azo reagents possess lower chemical hazard compared with typical azoReagents.

TL;DR: The first instance in which a redox-driven change in the complete chelating binding pocket has been observed in a ruthenium complex as well as with azo-based ligands is observed, showing the potential of these versatile azocarboxamide ligands to act as red ox-driven switches with possible relevance to electrocatalysis.

TL;DR: A general protocol to independently access stereoisomerically pure β'-hydroxy-β-amino acid derivatives that is based on dibutylboron triflate-mediated aldol reaction of suitably protected β-aminos acids bearing chiral oxazolidinone auxiliary is reported.