Plasmonic colours are structural colours that emerge from resonant interactions between light and metallic nanostructures. The engineering of plasmonic colours is a promising, rapidly emerging research field that could have a large technological impact. We highlight basic properties of plasmonic colours and recent nanofabrication developments, comparing technology-performance indicators for traditional and nanophotonic colour technologies. The structures of interest include diffraction gratings, nanoaperture arrays, thin films, and multilayers and structures that support Mie resonances and whispering-gallery modes. We discuss plasmonic colour nanotechnology based on localized surface plasmon resonances, such as gap plasmons and hybridized disk–hole plasmons, which allow for colour printing with sub-diffraction resolution. We also address a range of fabrication approaches that enable large-area printing and nanoscale lithography compatible with complementary metal-oxide semiconductor technologies, including nanoimprint lithography and self-assembly. Finally, we review recent developments in dynamically reconfigurable plasmonic colours and in the laser-induced post-processing of plasmonic colour surfaces. Plasmonic colours can be used to colour large surfaces, can be mass-produced and dynamically reconfigured, and can provide sub-diffraction resolution. In this Review, basic properties of plasmonic colours, different platforms supporting them and recent developments in the field are discussed.

Plasmonic colour generation

Plasmonic colour printing based on engineered metasurfaces has revolutionized colour display science due to its unprecedented subwavelength resolution and high-density optical data storage. However, advanced plasmonic displays with novel functionalities including dynamic multicolour printing, animations, and highly secure encryption have remained in their infancy. Here we demonstrate a dynamic plasmonic colour display technique that enables all the aforementioned functionalities using catalytic magnesium metasurfaces. Controlled hydrogenation and dehydrogenation of the constituent magnesium nanoparticles, which serve as dynamic pixels, allow for plasmonic colour printing, tuning, erasing and restoration of colour. Different dynamic pixels feature distinct colour transformation kinetics, enabling plasmonic animations. Through smart material processing, information encoded on selected pixels, which are indiscernible to both optical and scanning electron microscopies, can only be read out using hydrogen as a decoding key, suggesting a new generation of information encryption and anti-counterfeiting applications. Here Duanet al. demonstrate dynamic plasmonic colour displays using catalytic magnesium metasurfaces. Controlled hydrogenation and dehydrogenation of the constituent nanoparticles, which serve as dynamic pixels, allow plasmonic colour printing, tuning, erasing, restoration of colour and encoding of information.

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Dynamic plasmonic colour display.

In the wake of intense research on metamaterials the two-dimensional analogue, known as metasurfaces, has attracted progressively increasing attention in recent years due to the ease of fabrication and smaller insertion losses, while enabling an unprecedented control over spatial distributions of transmitted and reflected optical fields. Metasurfaces represent optically thin planar arrays of resonant subwavelength elements that can be arranged in a strictly or quasi periodic fashion, or even in an aperiodic manner, depending on targeted optical wavefronts to be molded with their help. This paper reviews a broad subclass of metasurfaces, viz. gradient metasurfaces, which are devised to exhibit spatially varying optical responses resulting in spatially varying amplitudes, phases and polarizations of scattered fields. Starting with introducing the concept of gradient metasurfaces, we present classification of different metasurfaces from the viewpoint of their responses, differentiating electrical-dipole, geometric, reflective and Huygens' metasurfaces. The fundamental building blocks essential for the realization of metasurfaces are then discussed in order to elucidate the underlying physics of various physical realizations of both plasmonic and purely dielectric metasurfaces. We then overview the main applications of gradient metasurfaces, including waveplates, flat lenses, spiral phase plates, broadband absorbers, color printing, holograms, polarimeters and surface wave couplers. The review is terminated with a short section on recently developed nonlinear metasurfaces, followed by the outlook presenting our view on possible future developments and perspectives for future applications.

Gradient metasurfaces: a review of fundamentals and applications.

Recently, color generation in resonant nanostructures have been intensively studied. Despite of their exciting progresses, the structural colors are usually generated by the plasmonic resonances of metallic nanoparticles. Due to the inherent plasmon damping, such plasmonic nanostructures are usually hard to create very distinct color impressions. Here we utilize the concept of metasurfaces to produce all-dielectric, low-loss, and high-resolution structural colors. We have fabricated TiO2 metasurfaces with electron-beam lithography and a very simple lift-off process. The optical characterizations showed that the TiO2 metasurfaces with different unit sizes could generate high reflection peaks at designed wavelengths. The maximal reflectance was as high as 64% with full width at half-maximum (fwhm) around 30 nm. Consequently, distinct colors have been observed in bright field and the generated colors covered the entire visible spectral range. The detailed numerical analysis shows that the distinct colors wer...

All-Dielectric Full-Color Printing with TiO2 Metasurfaces

Hybrid nanostructures composed of graphene or other two-dimensional (2D) nanomaterials and plasmonic metal components have been extensively studied. The unusual properties of 2D materials are associated with their atomically thin thickness and 2D morphology, and many impressive structures enable the metal nanomaterials to establish various interesting hybrid nanostructures with outstanding plasmonic properties. In addition, the hybrid nanostructures display unique optical characteristics that are derived from the close conjunction of plasmonic optical effects and the unique physicochemical properties of 2D materials. More importantly, the hybrid nanostructures show several plasmonic electrical effects including an improved photogeneration rate, efficient carrier transfer, and a plasmon-induced "hot carrier", playing a significant role in enhancing device performance. They have been widely studied for plasmon-enhanced optical signals, photocatalysis, photodetectors (PDs), and solar cells. In this review, the developments in the field of metal/2D hybrid nanostructures are comprehensively described. Preparation of hybrid nanostructures is first presented according to the 2D material type, as well as the metal nanomaterial morphology. The plasmonic properties and the enabled applications of the hybrid nanostructures are then described. Lastly, possible future research in this promising field is discussed.

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Hybrid nanostructures of metal/two-dimensional nanomaterials for plasmon-enhanced applications

Metallic nanostructures can be designed to effectively reflect different colors at deep-subwavelength scales. Such color manipulation is attractive for applications such as subwavelength color printing; however, challenges remain in creating saturated colors with a general and intuitive design rule. Here, we propose a simple design approach based on all-aluminum gap-plasmonic nanoantennas, which is capable of designing colors using knowledge of the optical properties of the individual antennas. We demonstrate that the individual-antenna properties that feature strong light absorption at two distinct frequencies can be encoded into a single subwavelength-pixel, enabling the creation of saturated colors, as well as a dark color in reflection, at the optical diffraction limit. The suitability of the designed color pixels for subwavelength printing applications is demonstrated by showing microscopic letters in color, the incident polarization and angle insensitivity, and color durability. Coupled with the low...

Full-Color Subwavelength Printing with Gap-Plasmonic Optical Antennas

We experimentally demonstrated an approach based on dipole and dual-quadrupole coupling to construct a planar metamaterial supporting multi-spectral plasmon induced transparency. The structure consists of two short silver wires (dipole) and two long silver wires (dual-quadrupole). The in-plane coupling between the dipole and the dual-quadrupole leads to two transmission windows even in the absorbance linewidth of the dipole. This phenomenon is well described and understood by numerical analyses and a classical oscillator model.

Multi-spectral plasmon induced transparency via in-plane dipole and dual-quadrupole coupling.

Conventional color image sensors employing absorptive color filters exhibit low overall light transmission, resulting in limited signal levels per sensor pixel. This issue is becoming critical beca...

High-Sensitivity Color Imaging Using Pixel-Scale Color Splitters Based on Dielectric Metasurfaces

We present an experimental demonstration of nanoscale gap plasmon resonators that consist of an individual suspended plasmonic nanowire (NW) over a metallic substrate. Our study demonstrates that the NW supports strong gap plasmon resonances of various gap sizes including single-nanometer-scale gaps. The obtained resonance features agree well with intuitive resonance models for near- and far-field regimes. We also illustrate that our suspended NW geometry is capable of constructing plasmonic coupled systems dominated by quasi-electrostatics.

Gap Plasmon Resonance in a Suspended Plasmonic Nanowire Coupled to a Metallic Substrate.

Polarization imaging is key for various applications ranging from biology to machine vision because it can capture valuable optical information about imaged environments, which is usually absent in intensity and spectral content. Conventional polarization cameras rely on a traditional single-eye imaging system with rotating polarizers, cascaded optics, or micropolarizer-patterned image sensors. These cameras, however, have two common issues. The first is low sensitivity resulting from the limited light utilization efficiency of absorptive polarizers or cascaded optics. The other is the difficulty in device miniaturization due to the fact that these devices require at least an optical-path length equivalent to the lens’s focal length. Here, we propose a polarization imaging system based on compound-eye metasurface optics and show how it enables the creation of a high-sensitivity, ultra-thin polarization camera. Our imaging system is composed of a typical image sensor and single metasurface layer for forming a vast number of images while sorting the polarization bases. Since this system is based on a filter-free, computational imaging scheme while dramatically reducing the optical-path length required for imaging, it overcomes both efficiency and size limitations of conventional polarization cameras. As a proof of concept, we demonstrated that our system improves the amount of detected light by a factor of ∼2, while reducing device thickness to ∼1/10 that of the most prevalent polarization cameras. Such a sensitive, compact, and passive device could pave the way toward the widespread adoption of polarization imaging in applications in which available light is limited and strict size constraints exist.

Masashi Miyata

Papers

Full-Color Subwavelength Printing with Gap-Plasmonic Optical Antennas

Multi-spectral plasmon induced transparency via in-plane dipole and dual-quadrupole coupling.

High-Sensitivity Color Imaging Using Pixel-Scale Color Splitters Based on Dielectric Metasurfaces

Gap Plasmon Resonance in a Suspended Plasmonic Nanowire Coupled to a Metallic Substrate.

Compound-eye metasurface optics enabling a high-sensitivity, ultra-thin polarization camera.