M
Michael J. Rourke
Researcher at University of Colorado Boulder
Publications - 2
Citations - 185
Michael J. Rourke is an academic researcher from University of Colorado Boulder. The author has contributed to research in topics: Nucleophile & Transmetalation. The author has an hindex of 2, co-authored 2 publications receiving 130 citations.
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Highly Stereospecific Cross-Coupling Reactions of Anomeric Stannanes for the Synthesis of C-Aryl Glycosides
TL;DR: It is demonstrated that configurationally stable anomeric stannanes undergo a stereospecific cross-coupling reaction with aromatic halides in the presence of a palladium catalyst with exceptionally high levels of stereocontrol.
Journal ArticleDOI
Glycosyl Cross-Coupling of Anomeric Nucleophiles: Scope, Mechanism, and Applications in the Synthesis of Aryl C-Glycosides
Feng Zhu,Jacob Rodriguez,Tianyi Yang,Ilia Kevlishvili,Eric S. Miller,Duk Yi,Sloane O'Neill,Michael J. Rourke,Peng Liu,Maciej A. Walczak +9 more
TL;DR: In this article, a novel approach to stereoselective synthesis of C-aryl glycosides capitalizing on the highly stereospecific reaction of anomeric nucleophiles was described.