https://digitalcommons.unl.edu/cgi/viewcontent.cgi?article=1131&context=usdoepub

A review of polymer electrolyte membrane fuel cells: Technology, applications,and needs on fundamental research

Since its first isolation in 2004, graphene has become one of the hottest topics in the field of materials science, and its highly appealing properties have led to a plethora of scientific papers. Among the many affected areas of materials science, this 'graphene fever' has influenced particularly the world of electrochemical energy-storage devices. Despite widespread enthusiasm, it is not yet clear whether graphene could really lead to progress in the field. Here we discuss the most recent applications of graphene - both as an active material and as an inactive component - from lithium-ion batteries and electrochemical capacitors to emerging technologies such as metal-air and magnesium-ion batteries. By critically analysing state-of-the-art technologies, we aim to address the benefits and issues of graphene-based materials, as well as outline the most promising results and applications so far.

The role of graphene for electrochemical energy storage

Review on recent progress of nanostructured anode materials for Li-ion batteries

In this comprehensive review, recent progress and developments on perfluorinated sulfonic-acid (PFSA) membranes have been summarized on many key topics. Although quite well investigated for decades, PFSA ionomers’ complex behavior, along with their key role in many emerging technologies, have presented significant scientific challenges but also helped create a unique cross-disciplinary research field to overcome such challenges. Research and progress on PFSAs, especially when considered with their applications, are at the forefront of bridging electrochemistry and polymer (physics), which have also opened up development of state-of-the-art in situ characterization techniques as well as multiphysics computation models. Topics reviewed stem from correlating the various physical (e.g., mechanical) and transport properties with morphology and structure across time and length scales. In addition, topics of recent interest such as structure/transport correlations and modeling, composite PFSA membranes, degradat...

New Insights into Perfluorinated Sulfonic-Acid Ionomers

Miniaturized energy storage is essential for the continuous development and further miniaturization of electronic devices. Electrochemical capacitors (ECs), also called supercapacitors, are energy storage devices with a high power density, fast charge and discharge rates, and long service life. Small-scale supercapacitors, or micro-supercapacitors, can be integrated with microelectronic devices to work as stand-alone power sources or as efficient energy storage units complementing batteries and energy harvesters, leading to wider use of these devices in many industries. In recent years, the research in this field has rapidly advanced and micro-supercapacitors with improved storage capacity and power density have been developed. The important factors affecting the performance of micro-supercapacitors are the intrinsic properties of electrode materials and electrolyte, architectural design of the device and the fabrication methods. This paper reviews the recent advances in fabrication of materials and devices and provides a critical analysis of reported performances of micro-supercapacitors.

Capacitive energy storage in micro-scale devices: recent advances in design and fabrication of micro-supercapacitors

Graphene has attracted extensive research interest due to its strictly 2-dimensional (2D) structure, which results in its unique electronic, thermal, mechanical, and chemical properties and potential technical applications. These remarkable characteristics of graphene, along with the inherent benefits of a carbon material, make it a promising candidate for application in electrochemical energy devices. This article reviews the methods of graphene preparation, introduces the unique electrochemical behavior of graphene, and summarizes the recent research and development on graphene-based fuel cells, supercapacitors and lithium ion batteries. In addition, promising areas are identified for the future development of graphene-based materials in electrochemical energy conversion and storage systems.

Graphene-based electrochemical energy conversion and storage: fuel cells, supercapacitors and lithium ion batteries.

At the beginning of the 21st century, fuel cells appear poised to meet the power needs of a variety of applications. Fuel cells are electrochemical devices that convert chemical energy to electricity and thermal energy. Fuel cell systems are available to meet the needs of applications ranging from portable electronics to utility power plants. In addition to the fuel cell stack itself, a fuel cell system includes a fuel processor and subsystems to manage air, water thermal energy, and power. The overall system is efficient at full and part-load, scaleable to a wide range of sizes, environmentally friendly, and potentially competitive with conventional technology in first cost. Promising applications for fuel cells include portable power, transportation, building cogeneration, and distributed power for utilities. For portable power a fuel cell coupled with a fuel container can offer a higher energy storage density and more convenience than conventional battery systems. In transportation applications, fuel cells offer higher efficiency and better part-load performance than conventional engines. In stationary power applications, low emissions permit fuel cells to be located in high power density areas where they can supplement the existing utility grid. Furthermore, fuel cell systems can be directly connected to a building to provide both power and heat with cogeneration efficiencies as high as 80%.

Michael W. Ellis

Papers

Graphene-based electrochemical energy conversion and storage: fuel cells, supercapacitors and lithium ion batteries.

Fuel cell systems: efficient, flexible energy conversion for the 21st century

A two-dimensional computational model of a PEMFC with liquid water transport

Single domain PEMFC model based on agglomerate catalyst geometry

Fatigue and creep to leak tests of proton exchange membranes using pressure-loaded blisters