M
Michel Bordeau
Researcher at University of Bordeaux
Publications - 64
Citations - 643
Michel Bordeau is an academic researcher from University of Bordeaux. The author has contributed to research in topics: Silylation & Electrosynthesis. The author has an hindex of 15, co-authored 64 publications receiving 590 citations. Previous affiliations of Michel Bordeau include Centre national de la recherche scientifique.
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Journal ArticleDOI
Selective electrochemical synthesis and reactivity of functional benzylic fluorosilylsynthons
Philippe Clavel,Guillaume Lessene,Claude Biran,Michel Bordeau,Nicolas Roques,Stéphane Trevin,Dominique de Montauzon +6 more
TL;DR: In this article, the influence of the cosolvent on the silylation selectivity was studied in the presence of an excess of TMSCl and in a THF/cosolvent mixture.
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Selective Electrosynthesis of (Trimethylsilyldifluoro)methylbenzene, a PhCF2- Precursor; Conditions for a Molar Scale Preparation without HMPA
Philippe Clavel,M.‐P. Leger‐Lambert,Claude Biran,Françoise Serein-Spirau,Michel Bordeau,Nicolas Roques,H. Marzouk +6 more
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L'électrosynthèse, une voie simple d'accès aux di- et polysilanes
TL;DR: In this paper, the reduction of chlorosilanes, at constant current intensity, in a single compartment cell fitted with a sacrificial aluminium anode, is described. But it is not a practical and convenient route to di-, tri-, and poly-silanes.
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The electrochemical reductive trimethylsilylation of aryl chlorides : a good route to aryltrimethylsilanes and a novel route to tris(trimethysilyl)cyclohexadienes
TL;DR: In this paper, the electroreductive trimethylsilylation of aryl chlorides R-C 6 H 4 Cl (R=H, o-Me, m-Me and p-Me) can be controlled so as to give, in good yields, either the corresponding arylstrimethylsilanes (products of the reduction of the carbon-chlorine bond) or mixtures of cis-and trans-tris(trimmethylsilyl)cyclohexa-1,3(or 1,4)-dienes
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Regio- and Stereoselective Synthesis of Silyl Enol Ethers Using a New Base Electrogenerated from Hexamethyldisilazane
TL;DR: The hexamethyldisilazane magnesium salt, a new base readily electrogenerated in an undivided cell fitted with a sacrificial magnesium anode, using a normally equilibrating medium (DME/15% vol HMPA mixture), exhibited a surprising regioselectivity leading to the less highly substituted silyl enol ethers from unsymmetrical ketones as mentioned in this paper.