Showing papers by "Mónica Giménez-Marqués published in 2023"
TL;DR: Two ultramicroporous 2D and 3D iron-based metal-based MOFs have been obtained by solvothermal synthesis using different ratios and concentrations of precursors as discussed by the authors .
Abstract: Two ultramicroporous 2D and 3D iron-based Metal–Organic Frameworks (MOFs) have been obtained by solvothermal synthesis using different ratios and concentrations of precursors. Their reduced pore space decorated with pendant pyridine from tangling isonicotinic ligands enables the combination of size-exclusion kinetic gas separation, due to their small pores, with thermodynamic separation, resulting from the interaction of the linker with CO2 molecules. This combined separation results in efficient materials for dynamic breakthrough gas separation with virtually infinite CO2/N2 selectivity in a wide operando range and with complete renewability at room temperature and ambient pressure.
1 citations
TL;DR: In this paper , low-valent metals are used as nodes in metal-organic frameworks (MOFs) to construct robust and porous structures, which is orthogonal to the commonly accepted strategy to robustness and robustness.
Abstract: Incorporating low-valent metals as nodes in metal-organic frameworks (MOFs) is orthogonal to the commonly accepted strategy to robust and porous structures. The electronic structures of low-valent metals are chemically unique...