Showing papers by "Nevin Gürbüz published in 2019"
TL;DR: The Ag(I)–NHC complexes (2a-d) showed a dose and time-dependent cytotoxic activity against all cell lines and the IC50s were higher in non-cancer cells, suggesting that complexes possessed noteworthy selectivity for human cancer cells.
36 citations
TL;DR: In this paper, four new benzimidazole-based N-heterocyclic carbene salts (1a-d) and their silver (I) complexes were synthesized.
32 citations
TL;DR: These silver and gold N-heterocyclic carbene complexes have been highlighted metal-based cancer therapeutic agent with unique structures and functions and provide exciting opportunities for discovering new type metalodrug.
24 citations
15 citations
TL;DR: In this paper, a series of ruthenium(II) complexes bearing N-heterocyclic carbene ligands with benzylic groups were prepared by transmetallation reactions between silver(I) Nhetercycleclic carbenes and [RuCl2(p-cymene)]2.
9 citations
6 citations
25 Sep 2019
6 citations
TL;DR: In this paper, ruthenium(II) complexes with N-heterocyclic carbene ligand were synthesized by transmetalation reactions between [RuCl2(p-cymene)]2.
Abstract: New ruthenium(II) complexes with N-heterocyclic carbene ligand were synthesized by transmetalation reactions between silver(I) N-heterocyclic carbene complexes and [RuCl2(p-cymene)]2. The complexes were characterized by physicochemical and spectroscopic methods. These ruthenium complexes were applied to the N-monoalkylation of aromatic amines with a wide range of primary alcohols under solvent-free conditions using the hydrogen borrowing strategy. The catalytic reactions using all ruthenium complexes resulted in N-monoalkylated products with high selectivities using furfuryl alcohol as the alkylating agent.
5 citations