Showing papers in "Inorganica Chimica Acta in 2019"
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TL;DR: In this article, materials Institute Lavoisier (MIL-125(Ti))/carbon nanotube (CNT) nanoporous composites were synthesized by hydrothermal method.
116 citations
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TL;DR: In this article, a coumarin-skeleton bis(salamo) ligand H4L was successfully prepared and characterized via the means of elemental analyses, single crystal X-ray crystallography, FT-IR, UV-Vis absorption spectroscopy and Hirshfeld surfaces analyses.
91 citations
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TL;DR: In this paper, the Schiff base ligands derived from hydrazone were synthesized and spectroscopically characterized by FT-IR, 1H NMR, UV-Vis spectroscopy, X-ray crystallography and cyclic voltammetry.
81 citations
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TL;DR: The need for a multidisciplinary approach in the battle against cancer using metallo-drugs by involving not only inorganic chemists, but also biochemists, molecular biologists and, of course, clinicians is emphasized.
58 citations
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TL;DR: In this article, a chemical sensor Z including benzothiazole fluorophore was synthesized and characterized with NMR and HRMS spectroscopic techniques, which exhibited fluorescence turn-on and ratiometric absorbance detection of Al3+ ǫions based on the combination mechanism of CHEF and ESIPT processes.
52 citations
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TL;DR: In this paper, three novel ferrocene-substituted thiosemicarbazones were synthesized and resolved into their single crystal structures for the estimation of unit cells, space groups, bond angles and bond lengths.
51 citations
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TL;DR: In this article, novel phthalocyanines having benzimidazole units which are known to have biological properties were synthesized, these newly synthesized molecules that were substituted by oxygen bridges were fully characterized.
45 citations
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TL;DR: In this article, a nano-sized metal organic framework-5 (MOF-5) was prepared in the presence of triethylamine (TEA) via consecutive combination of ultrasound (US) and microwave irradiation (MW) methods by exploiting the benefit of obtaining MOF5 in very short reaction times and high yields (∼95%).
43 citations
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TL;DR: In this article, a new and efficient magnetic nanocatalyst has been fabricated via covalent grafting of an aza-crown ether Cu(II) complex on silica coated iron oxide support.
43 citations
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TL;DR: In this article, the effect of tetrazole ligands on viability of the MCF-7 and Hep-2 cell lines was investigated in vitro by using elemental analysis, IR, EPR spectroscopy and X-ray diffraction.
42 citations
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TL;DR: In this paper, two new dicyanamide modulated zinc metal complexes [Zn4(LOMe)2(µ1-dca)2 (µ 1,5-dCA)2] were synthesized using H2vanen-type compartmental ligands.
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TL;DR: In this paper, two dicyanamide-interlaced tetranuclear Zn(II)-Schiff-base complexes were synthesized by using salicylaldimino type Schiff bases (H2LOMe) and H2LOEt) respectively.
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TL;DR: In this article, a new fumarato bridged Zn(II) coordination polymer viz. catena has been synthesized in purely aqueous medium at room temperature, which is structurally characterized by single crystal X-ray diffraction, FT-IR, electronic spectroscopy, PXRD and TGA.
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TL;DR: In this article, nano-sized NH2-MIL-53(Al) particles were conveniently synthesized in aqueous solution at ambient temperature with a widely applicable mixing method, and the morphology and character were examined with a series of techniques XRD patterns and TEM images.
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TL;DR: In this paper, two metal atoms bridged by 2-Mt ligands (μ2-N,S) in head-to-tail (for 1 and 2) and headto-head (for 3) manner were used to self-assemble a nuclear complex.
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TL;DR: In this article, a novel oxalate bridged supramolecular ternary complex has been synthesized from purely aqueous media and characterized using elemental analysis, spectroscopic (IR, UV-Vis-NIR and ESR) and single crystal X-ray diffraction techniques.
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TL;DR: In this paper, a guanidine base colorimetric and fluorescent bis Schiff base chemosensor L has been designed synthesized and characterized by elemental analyses, 1H NMR, FT-IR and ESI-MS spectral analysis.
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TL;DR: The Ag(I)–NHC complexes (2a-d) showed a dose and time-dependent cytotoxic activity against all cell lines and the IC50s were higher in non-cancer cells, suggesting that complexes possessed noteworthy selectivity for human cancer cells.
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TL;DR: In this paper, the structure of two N,N-diallyldithiocarbamato ligands bond to the tin ion in an anisobidentate fashion resulting in a highly distorted six coordinate geometry, best described as skew trapezoidal-bipyramidal geometry.
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TL;DR: In this paper, two coordination complexes of Cu(II and Co(II) involving 3,5-dimethyl pyrazole have been synthesized in purely aqueous medium at room temperature.
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TL;DR: In this article, two new copper coordination solids involving 1,10-phenanthroline (phen) and benzoate (bz) have been synthesized and characterized by X-ray crystal structure analysis, FT-IR, electronic spectra, and TGA.
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TL;DR: In this paper, the tridentate N-acyhydrazone derived from 4-hydroxy-benzohydrazide and 2-hydroxyl-3-methoxybenzaldehyde (H2L) was synthesized and characterized in the solid state and in solution by spectroscopic (FTIR, Ra, UV-vis, EPR) methods.
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TL;DR: In this article, a carbonized PANI with a coral-like nanostructure was formed over carbon nanotubes and graphene oxide (GO) surface, which exhibited the high specific capacitance of 465mF/cm−2 at a current density of 1.
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TL;DR: In this paper, a review of the role of weak non-covalent interactions in the structural diversity of coordination polymers is presented, where the authors provide an obvious idea about the correlation between weak non covalent interaction inside the architecture and the different structural diversity.
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TL;DR: In this paper, a dual approach comprising of experimental and computational techniques was used to report synthesized and characterizations of two novel nickel (II) [Ni(L)2] (1) and copper (II] [Cu(L 2] (2) coordination complexes, which are made through the coordination of 1-(E-(2, 4-dibromophenylimino) methyl) naphthalene-2-ol (HL) ligand.
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TL;DR: In this article, an aldehyde functionalized Al(III)-based luminescent metal-organic framework (MOF) denoted as CAU-10-CHO (1, CAU stands for Christian-Albrechts-University) was employed for the detection of toxic Cr2O72− ion in aqueous medium.
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TL;DR: The Schiff base 2-[(3-Methylamino-propylimino)-methyl]-phenol (HL) has been used for the synthesis of three dinuclear Cu(II) complexes as mentioned in this paper.
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TL;DR: In this article, two new Mn(II) coordination polymers viz. [Mn(p-NBz)2(4-CNpy)2]n (1) and [mn(n-NBp-nitrobenzoate, H3BTC] have been synthesized at room temperature and characterized by single crystal X-ray diffraction.
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TL;DR: The studies indicate intercalation mode of binding between complexes and DNA, which is complemented by molecular docked structure, which demonstrates that all complexes are effective against tested microorganisms.
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TL;DR: In this paper, the thermal destruction of giant polyoxometalate (POM) high-symmetry nanoclusters (toroidal Mo138 and Keplerates Mo132 and Mo72Fe30) was in situ investigated by Raman and IR spectroscopy.