Open quantum systems (OQSs) cannot always be described with the Markov approximation, which requires a large separation of system and environment time scales. An overview is given of some of the most important techniques available to tackle the dynamics of an OQS beyond the Markov approximation. Some of these techniques, such as master equations, Heisenberg equations, and stochastic methods, are based on solving the reduced OQS dynamics, while others, such as path integral Monte Carlo or chain mapping approaches, are based on solving the dynamics of the full system. The physical interpretation and derivation of the various approaches are emphasized, how they are connected is explored, and how different methods may be suitable for solving different problems is examined.

/pdf/dynamics-of-non-markovian-open-quantum-systems-1h281o731u.pdf

Dynamics of non-Markovian open quantum systems

Microwave spectroscopy experiments have been performed on two quantum levels of a macroscopic superconducting loop with three Josephson junctions. Level repulsion of the ground state and first excited state is found where two classical persistent-current states with opposite polarity are degenerate, indicating symmetric and antisymmetric quantum superpositions of macroscopic states. The two classical states have persistent currents of 0.5 microampere and correspond to the center-of-mass motion of millions of Cooper pairs.

/pdf/quantum-superposition-of-macroscopic-persistent-current-1li2s27wmk.pdf

Quantum Superposition of Macroscopic Persistent-Current States

Phase coherence is a fundamental concept in quantum mechanics. Understanding the loss of coherence is paramount for future quantum information processing. We studied the coherent dynamics of a single central spin (a nitrogen-vacancy center) coupled to a bath of spins (nitrogen impurities) in diamond. Our experiments show that both the internal interactions of the bath and the coupling between the central spin and the bath can be tuned in situ, allowing access to regimes with surprisingly different behavior. The observed dynamics are well explained by analytics and numerical simulations, leading to valuable insight into the loss of coherence in spin systems. These measurements demonstrate that spins in diamond provide an excellent test bed for models and protocols in quantum information.

https://science.sciencemag.org/content/sci/320/5874/352.full.pdf

Coherent Dynamics of a Single Spin Interacting with an Adjustable Spin Bath

The quantum dynamics of mesoscopic or macroscopic systems is always complicated by their coupling to many `environmental' modes. At low T these environmental effects are dominated by localized modes, such as nuclear and paramagnetic spins, and defects (which also dominate the entropy and specific heat). This environment, at low energies, maps onto a `spin bath' model. This contrasts with `oscillator bath' models (originated by Feynman and Vernon) which describe delocalized environmental modes such as electrons, phonons, photons, magnons, etc. The couplings to N spin bath modes are independent of N (rather than the ~O(1/(N )1/2 ) dependence typical of oscillator baths), and often strong. One cannot in general map a spin bath to an oscillator bath (or vice versa); they constitute distinct `universality classes' of quantum environment. We show how the mapping to spin bath models is made, and then discuss several examples in detail, including moving particles, magnetic solitons, nanomagnets, and SQUIDs, coupled to nuclear and paramagnetic spin environments. We then focus on the `central spin' model, which couples a central two-level system to a background spin bath. It is the spin bath analogue of the famous `spin-boson' oscillator model, and describes, e.g., the tunnelling dynamics of nanoscopic and mesoscopic magnets and superconductors. We show how to average over (or `integrate out') spin bath modes, using an operator instanton technique, to find the central spin dynamics. The formal manouevres involve four separate averages - each average corresponds physically to a different `decoherence' mechanism acting on the central spin dynamics. Each environmental spin has its own topological `spin phase', which by interacting with the phase of the central system, decoheres it - this can happen even without dissipation. We give analytic results for the central spin correlation functions, under various conditions. We then describe the application of this theory to magnetic and superconducting systems. Particular attention is given to recent work on tunnelling magnetic macromolecules, where the role of the nuclear spin bath in controlling the tunnelling is very clear; we also discuss other magnetic systems in the quantum regime, and the influence of nuclear and paramagnetic spins on flux dynamics in SQUIDs. Finally, we discuss decoherence mechanisms and coherence experiments in superconductors and magnets. We show that a spin bath environment causes decoherence even in the T 0 limit. Control of this decoherence will be essential in the effort to construct `qubits' for quantum computers.

/pdf/theory-of-the-spin-bath-4gipl0urbl.pdf

Theory of the spin bath

Experimental and theoretical progress toward quantum computation with spins in quantum dots (QDs) is reviewed, with particular focus on QDs formed in GaAs heterostructures, on nanowire-based QDs, and on self-assembled QDs. We report on a remarkable evolution of the field, where decoherence—one of the main challenges for realizing quantum computers—no longer seems to be the stumbling block it had originally been considered. General concepts, relevant quantities, and basic requirements for spin-based quantum computing are explained; opportunities and challenges of spin-orbit interaction and nuclear spins are reviewed. We discuss recent achievements, present current theoretical proposals, and make several suggestions for further experiments.

Prospects for Spin-Based Quantum Computing in Quantum Dots

The quantum dynamics of mesoscopic or macroscopic systems is always complicated by their coupling to many "environmental" modes.At low T these environmental effects are dominated by localised modes, such as nuclear and paramagnetic spins, and defects (which also dominate the entropy and specific heat). This environment, at low energies, maps onto a "spin bath" model. This contrasts with "oscillator bath" models (originated by Feynman and Vernon) which describe {\it delocalised} environmental modes such as electrons, phonons, photons, magnons, etc. One cannot in general map a spin bath to an oscillator bath (or vice-versa); they constitute distinct "universality classes" of quantum environment. We show how the mapping to spin bath models is made, and then discuss several examples in detail, including moving particles, magnetic solitons, nanomagnets, and SQUIDs, coupled to nuclear and paramagnetic spin environments. We show how to average over spin bath modes, using an operator instanton technique, to find the system dynamics, and give analytic results for the correlation functions, under various conditions. We then describe the application of this theory to magnetic and superconducting systems.Particular attention is given to recent work on tunneling magnetic macromolecules, where the role of the nuclear spin bath in controlling the tunneling is very clear; we also discuss other magnetic systems in the quantum regime, and the influence of nuclear and paramagnetic spins on flux dynamics in SQUIDs.

https://arxiv.org/pdf/cond-mat/0001080.pdf

Recent theory and experiment in crystals of molecular magnets suggest that fundamental tests of the decoherence mechanisms of macroscopic quantum phenomena may be feasible in these systems (which are also almost ideal quantum spin glasses). We review these, and suggest new experiments.

Nikolay Prokof'ev

Papers

Theory of the spin bath

Theory of the spin bath

Quantum Relaxation of Ensembles of Nanomagnets