Norihiro Tokitoh

TL;DR: The early silylene research was concerned largely with comparing the chemistry of the dihalosilylenes with that of carbenes, so it might be difficult to isolate metallylenes as stable compounds under ambient conditions.

TL;DR: In this paper, the synthesis, structure, and properties of stable silylenes are described together with those of related divalent species of the other Group 14 elements, and some detailed descriptions are allotted to new aspects in the relationship between the DVSs and the corresponding double-bond species of heavier Group 14 element.

TL;DR: An optically active propeller-shaped macrocyclic compound containing a planar chiral cyclophane core was synthesized, showing excellent chiroptical properties such as high fluorescence quantum efficiency and a large circularly polarized luminescence dissymmetry factor.

TL;DR: In this paper, lead halide complexes formed during the fabrication of perovskite (CH3NH3PbI3)-based solar cells were examined by single-crystal X-ray diffraction analysis.

TL;DR: A concise nickel-based synthesis of CPP and the first X-ray crystal structure of [12]CPP are reported, which is a concise, cost-effective, and scalable way of making CPPs.