IN view of the interest attaching to the vaporisation and diffusion of solids, the following observations may be worthy of record.

The Diffusion of Solids

Today, a large number of different steels are being processed by Additive Manufacturing (AM) methods. The different matrix microstructure components and phases (austenite, ferrite, martensite) and the various precipitation phases (intermetallic precipitates, carbides) lend a huge variability in microstructure and properties to this class of alloys. This is true for AM-produced steels just as it is for conventionally-produced steels. However, steels are subjected during AM processing to time-temperature profiles which are very different from the ones encountered in conventional process routes, and hence the resulting microstructures differ strongly as well. This includes a very fine and highly morphologically and crystallographically textured microstructure as a result of high solidification rates as well as non-equilibrium phases in the as-processed state. Such a microstructure, in turn, necessitates additional or adapted post-AM heat treatments and alloy design adjustments. In this review, we give an overview over the different kinds of steels in use in fusion-based AM processes and present their microstructures, their mechanical and corrosion properties, their heat treatments and their intended applications. This includes austenitic, duplex, martensitic and precipitation-hardening stainless steels, TRIP/TWIP steels, maraging and carbon-bearing tool steels and ODS steels. We identify areas with missing information in the literature and assess which properties of AM steels exceed those of conventionally-produced ones, or, conversely, which properties fall behind. We close our review with a short summary of iron-base alloys with functional properties and their application perspectives in Additive Manufacturing.

Steels in additive manufacturing: A review of their microstructure and properties

Revisiting fundamental welding concepts to improve additive manufacturing: From theory to practice

Additive manufacturing has revolutionized the manufacturing paradigm in recent years due to the possibility of creating complex shaped three-dimensional parts which can be difficult or impossible to obtain by conventional manufacturing processes. Among the different additive manufacturing techniques, wire and arc additive manufacturing (WAAM) is suitable to produce large metallic parts owing to the high deposition rates achieved, which are significantly larger than powder-bed techniques, for example. The interest in WAAM is steadily increasing, and consequently, significant research efforts are underway. This review paper aims to provide an overview of the most significant achievements in WAAM, highlighting process developments and variants to control the microstructure, mechanical properties, and defect generation in the as-built parts; the most relevant engineering materials used; the main deposition strategies adopted to minimize residual stresses and the effect of post-processing heat treatments to improve the mechanical properties of the parts. An important aspect that still hinders this technology is certification and nondestructive testing of the parts, and this is discussed. Finally, a general perspective of future advancements is presented.

Current Status and Perspectives on Wire and Arc Additive Manufacturing (WAAM)

The synergistic action and interplay of hydrogen embrittlement mechanisms in steels and iron: Localized plasticity and decohesion

Additive manufacturing using WAAM with AA5183 wire

Hydrogen diffusion and hydrogen influenced critical stress intensity in an API X70 pipeline steel welded joint – Experiments and FE simulations

Fiber laser-MIG hybrid welding of 5 mm 5083 aluminum alloy

Local brittle zones, i.e., martensite–austenite (M–A) islands, are formed within the coarse-grained heat-affected zone (CGHAZ) and the intercritically reheated CGHAZ (ICCGHAZ) during welding of many HSLA steels. In the current study, the M–A constituents in the microstructure of simulated ICCGHAZ of an API X80 pipeline steel were investigated using transmission electron microscopy and scanning electron microscopy. The focused ion beam technique was applied to make TEM specimens of M–A constituents that were located in the initiation sites of cleavage cracks. The main purpose of the study was to identify crack-initiation sites of cleavage fracture in ICCGHAZ and to prove the presence of M–A constituents in such initiation sites. Twinned martensite was detected in all local brittle zones that were investigated in the current study, demonstrating that they are M–A constituents. It was also demonstrated that the fracture initiation occurred preferentially at M–A constituents by a debonding mechanism rather than cracking of the M–A constituents.

Odd M. Akselsen

Papers

Additive manufacturing using WAAM with AA5183 wire

Hydrogen diffusion and hydrogen influenced critical stress intensity in an API X70 pipeline steel welded joint – Experiments and FE simulations

Fiber laser-MIG hybrid welding of 5 mm 5083 aluminum alloy

Cleavage Fracture Initiation at M–A Constituents in Intercritically Coarse-Grained Heat-Affected Zone of a HSLA Steel

3D cohesive modelling of hydrogen embrittlement in the heat affected zone of an X70 pipeline steel