Showing papers by "Peter S. White published in 1982"
76 citations
Journal Article•
34 citations
33 citations
TL;DR: Se2I4(Sb2F11)2 has been prepared and its structure determined by single crystal X-ray diffraction; the Se2I42+cation has an eclipsed S2O42-type structure with two Sel2+ units joined by a weak selenium-selenium bond as discussed by the authors.
Abstract: Se2I4(Sb2F11)2 has been prepared and its structure determined by single crystal X-ray diffraction; the Se2I42+cation has an eclipsed S2O42– type structure with two Sel2+ units joined by a weak selenium–selenium bond [2.841(2)A] and very weak iodine–iodine interactions [3.756(2), 3.661(2)A].
17 citations
TL;DR: In this article, the linear and bent VNO groups interconvert, and the linear VNO group necessarily contains at least one ring with less than η5hapticity, while the VNO decomposes in vacuo in tetrahydrofuran solution.
Abstract: cp2VX(NO)(cp = C5H5,X = Br, I) are fluxional molecules in which linear and bent VNO groups interconvert; the molecule with the linear VNO group necessarily contains at least one ring with less than η5hapticity, While cp2VI(NO) decomposes in vacuo in tetrahydrofuran solution to give [(cpVI)2{cpV(NO)}2(µ-O)4]whose X-ray crystal structure is reported.
6 citations
5 citations