1. Introduction and overview 2. Film stress and substrate curvature 3. Stress in anisotropic and patterned films 4. Delamination and fracture 5. Film buckling, bulging and peeling 6. Dislocation formation in epitaxial systems 7. Dislocation interactions and strain relaxation 8. Equilibrium and stability of surfaces 9. The role of stress in mass transport.

Thin Film Materials: Stress, Defect Formation and Surface Evolution

There has been a renaissance of interest in exploring highly efficient thermoelectric materials as a possible route to address the worldwide energy generation, utilization, and management. This review describes the recent advances in designing high-performance bulk thermoelectric materials. We begin with the fundamental stratagem of achieving the greatest thermoelectric figure of merit ZT of a given material by carrier concentration engineering, including Fermi level regulation and optimum carrier density stabilization. We proceed to discuss ways of maximizing ZT at a constant doping level, such as increase of band degeneracy (crystal structure symmetry, band convergence), enhancement of band effective mass (resonant levels, band flattening), improvement of carrier mobility (modulation doping, texturing), and decrease of lattice thermal conductivity (synergistic alloying, second-phase nanostructuring, mesostructuring, and all-length-scale hierarchical architectures). We then highlight the decoupling of th...

Rationally Designing High-Performance Bulk Thermoelectric Materials

Atmospheric-pressure plasmas are used in a variety of materials processes. Traditional sources include transferred arcs, plasma torches, corona discharges, and dielectric barrier discharges. In arcs and torches, the electron and neutral temperatures exceed 3000/spl deg/C and the densities of charge species range from 10/sup 16/-10/sup 19/ cm/sup -3/. Due to the high gas temperature, these plasmas are used primarily in metallurgy. Corona and dielectric barrier discharges produce nonequilibrium plasmas with gas temperatures between 50-400/spl deg/C and densities of charged species typical of weakly ionized gases. However, since these discharges are nonuniform, their use in materials processing is limited. Recently, an atmospheric-pressure plasma jet has been developed, which exhibits many characteristics of a conventional, low-pressure glow discharge. In the jet, the gas temperature ranges from 25-200/spl deg/C, charged-particle densities are 10/sup 11/-10/sup 12/ cm/sup -3/, and reactive species are present in high concentrations, i.e., 10-100 ppm. Since this source may be scaled to treat large areas, it could be used in applications which have been restricted to vacuum. In this paper, the physics and chemistry of the plasma jet and other atmospheric-pressure sources are reviewed.

/pdf/the-atmospheric-pressure-plasma-jet-a-review-and-comparison-4n3xn1jiyb.pdf

The atmospheric-pressure plasma jet: a review and comparison to other plasma sources

Atmospheric pressure plasmas: A review

This review summarises the research work carried out in the field of carbon nanotube (CNT) metal matrix composites (MMCs). Much research has been undertaken in utilising CNTs as reinforcement for composite material. However, CNT-reinforced MMCs have received the least attention. These composites are being projected for use in structural applications for their high specific strength as well as functional materials for their exciting thermal and electrical characteristics. The present review focuses on the critical issues of CNT-reinforced MMCs that include processing techniques, nanotube dispersion, interface, strengthening mechanisms and mechanical properties. Processing techniques used for synthesis of the composites have been critically reviewed with an objective to achieve homogeneous distribution of carbon nanotubes in the matrix. The mechanical property improvements achieved by addition of CNTs in various metal matrix systems are summarised. The factors determining strengthening achieved by CNT reinforcement are elucidated as are the structural and chemical stability of CNTs in different metal matrixes and the importance of the CNT/metal interface has been reviewed. The importance of CNT dispersion and its quantification is highlighted. Carbon nanotube reinforced MMCs as functional materials are summarised. Future work that needs attention is addressed.

Carbon nanotube reinforced metal matrix composites - a review

This article intends to summarize our actual knowledge in plasma spraying with an emphasis on the points where work is still in progress. It presents successively: the plasma torches with the resulting plasma jets and their interactions with the surrounding environment; the powder injection with the heat, momentum and mass transfers between particles and first plasma jets and then plasma plume; the particles flattening and solidification, forming splats which then layer to form the coating; the latest developments related to the production of plasma sprayed finely structured coatings.

http://iopscience.iop.org/article/10.1088/0022-3727/37/9/R02/pdf

Understanding plasma spraying

The Plasma State. Basic Atomic and Molecular Theory. Kinetic Theory. Fundamental Concepts in Gaseous Electronics. Derivation of the Plasma Equations. Thermodynamic Properties. Transport Properties. Radiation Transport. Index.

Thermal Plasmas: Fundamentals and Applications

https://www.springer.com/cda/content/document/productFlyer/productFlyer_978-0-387-28319-7.pdf?SGWID=0-0-1297-175214260-0

Thermal Spray Fundamentals

This paper summarizes our knowledge at the beginning of 2003 about splat formation. First, the analytical and numerical models related to the impact and flattening of single particles on smooth or rough substrates with different tilting are recalled. Then, the different diagnostic methods, including imaging, are briefly described. The last part of the paper is devoted to the results and their discussion. Studies are related to the effect of various parameters on particle flattening. They include the characteristics of particles prior to impact: normal impact velocity, temperature, molten state, oxidation state, etc.; the parameters related to the substrate: tilting angle, roughness, oxide layer composition, thickness and crystallinity, desorption of adsorbates and condensates, wetting properties between impacting particle and substrate, etc.; and, finally, the parameters related to the heat exchange between the flattening particle and the substrate. They depend on previous parameters and control the propagation of the solidification front within the flattening particle, eventually modifying its liquid flow. It is obvious from this review that, if our understanding of the involved phenomena has been drastically improved during the last years, many points have still to be clarified. This is of primary importance because all the coating properties are linked to the particle flattening, splat formation, and layering.

Knowledge concerning splat formation : An invited review

Although many thermal plasma processes have been developed for industrial applications, the wide acceptance as a manufacturing technology is prevented due to economical and competitive reasons, and/or reproducibility and reliability aspects. This paper is devoted to an assessment of the present knowledge in the following topics: (1) plasma torch and performance of blown arc (dc or ac), transferred arc and radio frequency torches; (2) established industrial applications with special emphasis on cutting, welding, spraying, transferred arc reclamation, reheating and purification, reheating metal melts, smelting reduction, chemical operations, and waste destruction; (3) recent developments in the knowledge of fundamental processes in plasma torches with power sources, cathodes (hot and cold), anodes (static and dynamic behavior), and torch components; (4) modeling-thermodynamic and transport properties, plasma flow with and without the Maxwell's equations; (5) measurement techniques including emission and absorption spectroscopy, laser scattering, enthalpy probes, video cameras, spectral analysis, shadowgraphy, and particle diagnostics either in flight with statistical measurements and those giving characteristics of a single particle upon flattening on a substrate; and (6) plasma-processing development in the presently used industrial processes and also in prospective processes with surface hardening, ultrafine powder production, plasma-assisted CVD, and plasma-fluidized or spouted bed reactors.

Pierre Fauchais

Papers

Understanding plasma spraying

Thermal Plasmas: Fundamentals and Applications

Thermal Spray Fundamentals

Knowledge concerning splat formation : An invited review

Thermal plasmas