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Praseetha Mathoor Illam
Researcher at Indian Institute of Technology Madras
Publications - 9
Citations - 153
Praseetha Mathoor Illam is an academic researcher from Indian Institute of Technology Madras. The author has contributed to research in topics: Carbene & Transfer hydrogenation. The author has an hindex of 4, co-authored 7 publications receiving 81 citations. Previous affiliations of Praseetha Mathoor Illam include Indian Institutes of Technology.
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Ruthenium(II) Complexes of Heteroditopic N-Heterocyclic Carbene Ligands: Efficient Catalysts for C-N Bond Formation via a Hydrogen-Borrowing Strategy under Solvent-Free Conditions.
TL;DR: The synthesized ruthenium(II) complexes 3 are found to be highly efficient for C-N bond formation across a wide range of primary amine and alcohol substrates under solvent-free conditions, and among all of the complexes studied here, catalyst 3a with a mesityl substituent displayed maximum activity.
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Effect of Ancillary Ligand in Cyclometalated Ru(II)-NHC-Catalyzed Transfer Hydrogenation of Unsaturated Compounds.
TL;DR: This is the first systematic study on the effect of stereoelectronic tuning of ancillary orthometalated NHC ligand in Ru(II)-catalyzed transfer hydrogenations of various types of unsaturated compounds with broad substrate scope.
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Heteroditopic Ru(II)– and Ir(III)–NHCComplexes with Pendant 1,2,3-Triazole/Triazolylidene Groups: StereoelectronicImpact on Transfer Hydrogenation of Unsaturated Compounds
TL;DR: In this article, the Ru(II)/Ir(III) complexes based on tNHC and 1,2,3-traizol-5-ylidene (tzNHC) were developed.
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Transition metal complexes of a bis(carbene) ligand featuring 1,2,4-triazolin-5-ylidene donors: structural diversity and catalytic applications
TL;DR: Complexes 5 and 6 represent the first examples of a stable diorthometalated binuclear IrIII/RuII-complex supported by 1,2,4-triazolin-5-ylidene donors and the synthesized IrIII-NHC complex 5 is found to be more effective than its RuII-analogue for the reduction of a range of alkenes/alkynes via the transfer hydrogenation strategy.
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Electronically Tuneable Orthometalated RuII-NHC Complexes as Efficient Catalysts for the C-C and C-N Bond Formations via Borrowing Hydrogen Strategy
TL;DR: In this paper, the catalytic activities of a series of simple and electronically tuneable cyclometalated RuII-NHC complexes (2a-d) were explored in various C-C/N bond formations following the borrowing hydrogen process.