A laser velocity interferometer instrumentation system has been developed which can measure the velocity history of either spectrally or diffusely reflecting surfaces. The system provides two interferometer fringe signals in quadrature to improve resolution and to distinguish between acceleration and deceleration. Accuracies of 2% or better are attainable for peak surface velocities of 0.2 mm/μsec or more. The system has been applied to the measurement of free surface motion in plate‐impact experiments, and to the measurement of the velocity history of a projectile during its acceleration down a long gun barrel.

Laser interferometer for measuring high velocities of any reflecting surface

Advances in science and technology of modern energetic materials: an overview.

Electromagnetic forming—A review

We have built a high-speed velocimeter that has proven to be compact, simple to operate, and fairly inexpensive. This diagnostic is assembled using off-the-shelf components developed for the telecommunications industry. The main components are fiber lasers, high-bandwidth high-sample-rate digitizers, and fiber optic circulators. The laser is a 2W cw fiber laser operating at 1550nm. The digitizers have 8GHz bandwidth and can digitize four channels simultaneously at 20GS∕s. The maximum velocity of this system is ∼5000m∕s and is limited by the bandwidth of the electrical components. For most applications, the recorded beat frequency is analyzed using Fourier transform methods, which determine the time response of the final velocity time history. Using the Fourier transform method of analysis allows multiple velocities to be observed simultaneously. We have obtained high-quality data on many experiments such as explosively driven surfaces and gas gun assemblies.

Compact system for high-speed velocimetry using heterodyne techniques

Review of experimental techniques for high rate deformation and shock studies

The shock‐wave propagation characteristics of polymethyl methacrylate (PMMA), fused silica, and sapphire were measured for both compressive and rarefaction waves using plate‐impact experiments and interferometer instrumentation techniques The peak stress levels in the experiments were 22, 65, and 120 kbar, respectively The high‐resolution measurements of the stress wave profiles showed the PMMA to be a complex material whose wave propagation is influenced by nonlinearity, strain‐rate dependence, and elastic‐plastic effects in which plastic working increases the zero‐pressure volume of the material The fused silica is very well characterized as a nonlinear elastic material having the interesting property of propagating stable rarefaction shock waves The sapphire was nearly linear elastic to 120 kbar The use of these three transparent materials as ``windows'' in laser interferometer instrumented shock‐wave studies of other materials is discussed The effect of the shock‐induced variation of the index o

Shock‐Wave Studies of PMMA, Fused Silica, and Sapphire

Mechanochemical and biocatalytic approaches in modern research are two major assets to develop greener processes. In the present study, these modular tools of sustainability are pointed toward the production of versatile and daily employed compounds such as surfactants. Toward this aim, glycolipids, a class of nonionic surfactants composed of ubiquitous and primary metabolites such as sugar and fatty acid moieties, represent a promising alternative to petroleum-derived surface-active agents. Therefore, the combination of biocatalysis with mechanochemistry aiming at glycolipid synthesis seemed a logical step that was taken in this study for the first time. The monoacylated model compound glucose-6-O-decanoate was synthesized with the help of a bead mill apparatus using two different unconventional dissolved reaction systems, namely, menthol-based hydrophobic deep eutectic solvents and 2-methyl-2-butanol, thus reaching up to 12% yield in the latter based on the conversion of vinyl decanoate, after only 90 min of reaction. In addition, a neat reaction system using an excess of vinylated fatty ester as an adjuvant allowed a 27 mM/h space-time yield. The overall significant increase in productivities, up to 6 times, compared to standard heating and shaking methods, shows the tremendous potential of mechanoenzymatic synthesis.

https://pubs.acs.org/doi/pdf/10.1021/acssuschemeng.2c01727

Lipase-Mediated Mechanoenzymatic Synthesis of Sugar Esters in Dissolved Unconventional and Neat Reaction Systems

Glycolipids are a class of biodegradable biosurfactants that are non-toxic and based on renewables, making them a sustainable alternative to petrochemical surfactants. Enzymatic synthesis allows a tailor-made production of these versatile compounds using sugar and fatty acid building blocks with rationalized structures for targeted applications. Therefore, glycolipids can be comprehensively designed to outcompete conventional surfactants regarding their physicochemical properties. However, enzymatic glycolipid processes are struggling with both sugars and fatty acid solubilities in reaction media. Thus, continuous flow processes represent a powerful tool in designing efficient syntheses of sugar esters. In this study, a continuous enzymatic glycolipid production catalyzed by Novozyme 435® is presented as an unprecedented concept. A biphasic aqueous–organic system was investigated, allowing for the simultaneous solubilization of sugars and fatty acids. Owing to phase separation, the remaining non-acylated glucose was easily separated from the product stream and was refed to the reactor forming a closed-loop system. Productivity in the continuous process was higher compared to a batch one, with space–time yields of up to 1228 ± 65 µmol/L/h. A temperature of 70 °C resulted in the highest glucose-6-O-decanoate concentration in the Packed Bed Reactor (PBR). Consequently, the design of a continuous biocatalytic production is a step towards a more competitive glycolipid synthesis in the aim for industrialization.

/pdf/continuous-flow-glycolipid-synthesis-using-a-packed-bed-fueoazs3.pdf

Continuous Flow Glycolipid Synthesis Using a Packed Bed Reactor

Glycolipids can be synthetized in deep eutectic solvents (DESs) as they possess low water content allowing a reversed lipase activity and thus enables ester formation. Based on this principle, honey can also serve as a media for glycolipid synthesis. Indeed, this supersaturated sugar solution is comparable in terms of physicochemical properties to the sugar-based DESs. Honey-based products being commercially available for therapeutic applications, it appears interesting to enhance its bioactivity. In the current work, we investigate if enriching medical grade honey with in situ enzymatically-synthetized glycolipids can improve the antimicrobial property of the mixture. The tested mixtures are composed of Manuka honey that is enriched with octanoate, decanoate, laurate, and myristate sugar esters, respectively dubbed GOH, GDH, GLH, and GMH. To characterize the bioactivity of those mixtures, first a qualitative screening using an agar well diffusion assay has been performed with methicillin-resistant Staphylococcus aureus, Bacillus subtilis, Candida bombicola, Escherichia coli, and Pseudomonas putida which confirmed considerably enhanced susceptibility of these micro-organisms to the different glycolipid enriched honey mixtures. Then, a designed biosensor E. coli strain that displays a stress reporter system consisting of three stress-specific inducible, red, green, and blue fluorescent proteins which respectively translate to physiological stress, genotoxicity, and cytotoxicity was used. Bioactivity was, therefore, characterized, and a six-fold enhancement of the physiological stress that was caused by GOH compared to regular Manuka honey at a 1.6% (v/v) concentration was observed. An antibacterial agar well diffusion assay with E. coli was performed as well and demonstrated an improved inhibitory potential with GOH upon 20% (v/v) concentration.

https://www.mdpi.com/1422-0067/23/19/12031/pdf?version=1665461069

R. E. Hollenbach

Papers

Laser interferometer for measuring high velocities of any reflecting surface

Shock‐Wave Studies of PMMA, Fused Silica, and Sapphire

Lipase-Mediated Mechanoenzymatic Synthesis of Sugar Esters in Dissolved Unconventional and Neat Reaction Systems

Continuous Flow Glycolipid Synthesis Using a Packed Bed Reactor

Enhanced Bioactivity of Tailor-Made Glycolipid Enriched Manuka Honey