R
R.J.M. Klein Gebbink
Researcher at Utrecht University
Publications - 38
Citations - 733
R.J.M. Klein Gebbink is an academic researcher from Utrecht University. The author has contributed to research in topics: Catalysis & Palladium. The author has an hindex of 14, co-authored 38 publications receiving 706 citations. Previous affiliations of R.J.M. Klein Gebbink include Radboud University Nijmegen & Johns Hopkins University.
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Journal ArticleDOI
A 'Dendritic Effect' in Homogeneous Catalysis with Carbosilane-Supported Arylnickel (II) Catalysts: Observation of Active-Site Proximity Effects in Atom-Transfer Radical Addition
G. van Koten,Arjan W. Kleij,Robert A. Gossage,R.J.M. Klein Gebbink,N. Brinkmann,Eduard J. Reijerse,Udo Kragl,Martin Lutz,Anthony L. Spek +8 more
TL;DR: In this article, the authors showed that the deactivation of polylithiated, carbosilane (CS) dendrimers is caused by irreversible formation of catalytically inactive Ni(III) sites on the periphery of these dendrilers.
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Halide-Assisted Macrocyclic Ring Formation in Cyclometalated Carbosilane Dendrimers with 1-[C6H3(CH2NMe2)-4-(PdCl)-3] Peripheral Groups: Application as Aldol Condensation Catalysts
G. van Koten,Arjan W. Kleij,R.J.M. Klein Gebbink,P.A.J. van den Nieuwenhuijzen,Huub Kooijman,Martin Lutz,A. L. Spek +6 more
TL;DR: A series of cyclopalladated carbosilane dendrimers functionalized with monoanionic [C6H4(CH2NMe2)-4]- (= CN) C,N-chelating ligands via a multiple and selective C-H bond activation process have been prepared in this paper.
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Synthesis, Structure, and Catalytic Performance of Diastereopure Five-Coordinated NCN-Pincer Palladium(II) Complexes Bearing Bulky Amino Acid Substituents
Silvia Gosiewska,S.D. Herreras Martinez,Martin Lutz,Anthony L. Spek,Remco W. A. Havenith,G.P.M. van Klink,G. van Koten,R.J.M. Klein Gebbink +7 more
TL;DR: New chiral NCN-pincer palladium complexes containing bulky diphenylhydroxymethyl pyrrolidinyl moieties as chiral auxiliaries have been synthesized.
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Hetero-multimetallic Tetrakis(SCS-pincer palladium)-(Metallo)porphyrin Hybrids. Tunable Precatalysts in a Heck Reaction
TL;DR: In this paper, a series of meso-tetrakis(SCS-pincer PdCl)−(metallo)porphyrin hybrids have been synthesized using two distinct synthetic routes.
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Chiral Amino Alcohol Derived Bis-phosphoramidite Pincer Palladium Complexes and Their Applications in Asymmetric Allylation of Aldimines
TL;DR: In this paper, a P-stereogenic bis-phosphoramidite pincer palladium complexes were derived from (S)-(−)-α,α-diphenyl-2-pyrrolidinemethanol and (S)(+)-indolinemethyl-indolinerethanol.