Systemic insecticides are applied to plants using a wide variety of methods, ranging from foliar sprays to seed treatments and soil drenches. Neonicotinoids and fipronil are among the most widely used pesticides in the world. Their popularity is largely due to their high toxicity to invertebrates, the ease and flexibility with which they can be applied, their long persistence, and their systemic nature, which ensures that they spread to all parts of the target crop. However, these properties also increase the probability of environmental contamination and exposure of nontarget organisms. Environmental contamination occurs via a number of routes including dust generated during drilling of dressed seeds, contamination and accumulation in arable soils and soil water, runoff into waterways, and uptake of pesticides by nontarget plants via their roots or dust deposition on leaves. Persistence in soils, waterways, and nontarget plants is variable but can be prolonged; for example, the half-lives of neonicotinoids in soils can exceed 1,000 days, so they can accumulate when used repeatedly. Similarly, they can persist in woody plants for periods exceeding 1 year. Breakdown results in toxic metabolites, though concentrations of these in the environment are rarely measured. Overall, there is strong evidence that soils, waterways, and plants in agricultural environments and neighboring areas are contaminated with variable levels of neonicotinoids or fipronil mixtures and their metabolites (soil, parts per billion (ppb)-parts per million (ppm) range; water, parts per trillion (ppt)-ppb range; and plants, ppb-ppm range). This provides multiple routes for chronic (and acute in some cases) exposure of nontarget animals. For example, pollinators are exposed through direct contact with dust during drilling; consumption of pollen, nectar, or guttation drops from seed-treated crops, water, and consumption of contaminated pollen and nectar from wild flowers and trees growing near-treated crops. Studies of food stores in honeybee colonies from across the globe demonstrate that colonies are routinely and chronically exposed to neonicotinoids, fipronil, and their metabolites (generally in the 1–100 ppb range), mixed with other pesticides some of which are known to act synergistically with neonicotinoids. Other nontarget organisms, particularly those inhabiting soils, aquatic habitats, or herbivorous insects feeding on noncrop plants in farmland, will also inevitably receive exposure, although data are generally lacking for these groups. We summarize the current state of knowledge regarding the environmental fate of these compounds by outlining what is known about the chemical properties of these compounds, and placing these properties in the context of modern agricultural practices.

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Environmental fate and exposure; neonicotinoids and fipronil

Murugesu Sivapalan,* Hubert H. G. Savenije and Gunter Bloschl 1 Department of Civil and Environmental Engineering, Department of Geography, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA 2 Department of Civil and Environmental Engineering, University of Technology Sydney, Broadway, NSW 2007, Australia 3 Department of Water Management, Faculty of Civil Engineering and Geosciences, Delft University of Technology, Delft, The Netherlands 4 Institute for Hydraulic and Water Resources Engineering, Vienna University of Technology, Vienna, Austria

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Socio‐hydrology: A new science of people and water

Biodiversity is a challenging field of research. Approaches are manifold and mostly cover few aspects of the total wealth of phenomena only. The mapping of the vascular plants and the inventory of Basidiomycota in Bavaria are projects to be mentioned in this context as one part of the commitment of the author. In the following article the author describes further activities during his lifework in regard A. Bresinsky (*) Institute of Botany of University of Regensburg, D-93040, Regensburg, Germany e-mail: abresinsky@t-online.de U. Lüttge et al. (eds.), Progress in Botany, Progress in Botany 75, DOI 10.1007/978-3-642-38797-5_1, © Springer-Verlag Berlin Heidelberg 2014 3 to ant–plant interactions resulting in dispersal and distribution of plants, and moreover, in respect to speciation and to evolution of high ranked taxa within the fungi, discussed mainly in relation to the genus Pleurotus and the order Boletales. In fungi the investigations include breeding systems, isolation barriers, polyploidy, pigment patterns and DNA phylogeny. The pigment patterning in Boletales correlates well with the phylogeny as revealed by DNA analysis of selected gene sections.

Progress in Botany

Scales and processes of water and sediment redistribution in drylands: results from the Rambla Honda field site in Southeast Spain

On 2017 August 17, gravitational waves were detected from a binary neutron star merger, GW170817, along with a coincident short gamma-ray burst, GRB170817A. An optical transient source, Swope Supernova Survey 17a (SSS17a), was subsequently identified as the counterpart of this event. We present ultraviolet, optical and infrared light curves of SSS17a extending from 10.9 hours to 18 days post-merger. We constrain the radioactively-powered transient resulting from the ejection of neutron-rich material. The fast rise of the light curves, subsequent decay, and rapid color evolution are consistent with multiple ejecta components of differing lanthanide abundance. The late-time light curve indicates that SSS17a produced at least ~0.05 solar masses of heavy elements, demonstrating that neutron star mergers play a role in r-process nucleosynthesis in the Universe.

Light Curves of the Neutron Star Merger GW170817/SSS17a: Implications for R-Process Nucleosynthesis

This work was undertaken to determine the kinds and amount of substances that would account for the previously demonstrated differential growth of Claviceps purpurea on guttation fluids from Rosen rye, Genesee wheat, and Traill barley seedlings. Chromatographic methods were used for determining amino acids and sugars, spot tests and spectrometric methods for inorganic materials, and microbiological methods for vitamins. Total sugar content is about equal in rye and barley fluids, but lower in wheat. Glucose is the principal sugar component of the rye and barley fluids and galactose highest in wheat. Most of the amino acid in all 3 fluids is aspartic acid or asparagine. Barley fluid is far higher than the other 2 in total amino acids, with wheat the lowest. Most inorganic elements are found to be highest in barley and lowest in wheat, with the exception of iron where rye is highest and barley lowest. Barley fluid is highest in choline, p -aminobenzoic acid, thiamine, and uracil, while rye is highest in inositol and pyridoxine. Wheat is much lower than the other 2 in choline and inositol.

Composition of Guttation Fluid from Rye, Wheat, and Barley Seedlings

Theory and Hypothesis.

The $\ensuremath{\beta}$-decay intensity of $^{70}\mathrm{Co}$ was measured for the first time using the technique of total absorption spectroscopy. The large $\ensuremath{\beta}$-decay $Q$ value [12.3(3) MeV] offers a rare opportunity to study $\ensuremath{\beta}$-decay properties in a broad energy range. Two surprising features were observed in the experimental results, namely, the large fragmentation of the $\ensuremath{\beta}$ intensity at high energies, as well as the strong competition between $\ensuremath{\gamma}$ rays and neutrons, up to more than 2 MeV above the neutron-separation energy. The data are compared to two theoretical calculations: the shell model and the quasiparticle random phase approximation (QRPA). Both models seem to be missing a significant strength at high excitation energies. Possible interpretations of this discrepancy are discussed. The shell model is used for a detailed nuclear structure interpretation and helps to explain the observed $\ensuremath{\gamma}$-neutron competition. The comparison to the QRPA calculations is done as a means to test a model that provides global $\ensuremath{\beta}$-decay properties for astrophysical calculations. Our work demonstrates the importance of performing detailed comparisons to experimental results, beyond the simple half-life comparisons. A realistic and robust description of the $\ensuremath{\beta}$-decay intensity is crucial for our understanding of nuclear structure as well as of $r$-process nucleosynthesis.

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Strong Neutron-γ Competition above the Neutron Threshold in the Decay of 70 Co

Antibacterial Substances in Organs of Higher Plants.

Neutron-capture reactions on very neutron-rich nuclei are essential for heavy-element nucleosynthesis through the rapid neutron-capture process, now shown to take place in neutron-star merger events. For these exotic nuclei, radiative neutron capture is extremely sensitive to their $\ensuremath{\gamma}$-emission probability at very low $\ensuremath{\gamma}$ energies. In this work, we present measurements of the $\ensuremath{\gamma}\text{-decay}$ strength of $^{70}\mathrm{Ni}$ over the wide range $1.3\ensuremath{\le}{E}_{\ensuremath{\gamma}}\ensuremath{\le}8$ MeV. A significant enhancement is found in the $\ensuremath{\gamma}\text{-decay}$ strength for transitions with ${E}_{\ensuremath{\gamma}}l3$ MeV. At present, this is the most neutron-rich nucleus displaying this feature, proving that this phenomenon is not restricted to stable nuclei. We have performed $E1$-strength calculations within the quasiparticle time-blocking approximation, which describe our data above ${E}_{\ensuremath{\gamma}}\ensuremath{\simeq}5$ MeV very well. Moreover, large-scale shell-model calculations indicate an $M1$ nature of the low-energy $\ensuremath{\gamma}$ strength. This turns out to be remarkably robust with respect to the choice of interaction, truncation, and model space, and we predict its presence in the whole isotopic chain, in particular the neutron-rich $^{72,74,76}\mathrm{Ni}$.

R. Lewis

Papers

Composition of Guttation Fluid from Rye, Wheat, and Barley Seedlings

Theory and Hypothesis.

Strong Neutron-γ Competition above the Neutron Threshold in the Decay of 70 Co

Antibacterial Substances in Organs of Higher Plants.

Enhanced low-energy γ -decay strength of Ni 70 and its robustness within the shell model