THE DESIGN AND ANALYSIS OF EXPERIMENTS. By Oscar Kempthorne. New York, John Wiley and Sons, Inc., 1952. 631 pp. $8.50. This book by a teacher of statistics (as well as a consultant for \"experimenters\") is a comprehensive study of the philosophical background for the statistical design of experiment. It is necessary to have some facility with algebraic notation and manipulation to be able to use the volume intelligently. The problems are presented from the theoretical point of view, without such practical examples as would be helpful for those not acquainted with mathematics. The mathematical justification for the techniques is given. As a somewhat advanced treatment of the design and analysis of experiments, this volume will be interesting and helpful for many who approach statistics theoretically as well as practically. With emphasis on the \"why,\" and with description given broadly, the author relates the subject matter to the general theory of statistics and to the general problem of experimental inference. MARGARET J. ROBERTSON

The Design and Analysis of Experiments

A comparative evaluation of different biomasses allows the choice that presents the best potential as fuel for energy production. The knowledge of the thermal and kinetics parameters of the biomass in the process of thermal conversion is fundamental as their chemical and physical characterization. Various methodologies have been developed for the determination of kinetic parameters as apparent activation energy and reaction order from the thermogravimetric analysis. In this work, the apparent activation energy needed to break the bonds of hemicelluloses and cellulose of rice husk and elephant grass during the thermal conversion was evaluated according to the kinetics models of Flynn and Wall and Model Free Kinetics developed by Vyazovkin. The biomass elephant grass and rice husk were characterized for moisture, ash and volatile matter by ASTM E871, ASTM E1755, ASTM E872, respectively, and fixed carbon by difference. The percentage of carbon, hydrogen, nitrogen, and oxygen were determined by ultimate analysis. The elephant grass showed to be more suitable for production of bio-oil through pyrolysis due to the higher percentage of volatile, less ash content and less energy required to break the bonds of hemicellulose and cellulose than rice husk in the thermal conversion process.

Characterization and comparative study of pyrolysis kinetics of the rice husk and the elephant grass

Comparison of the thermal degradation behaviors and kinetics of palm oil waste under nitrogen and air atmosphere in TGA-FTIR with a complementary use of model-free and model-fitting approaches

From the conventional use of biomass in the form of heating to the modern day use of biomass in the form of electricity generation and biofuel production, biomass has always been part of the evolution of mankind Modern day use of biomass is gradually becoming more complex, and engineering played an important role in defining different directions This review provides an overall view of biomass utilization through thermal treatment including combustion, pyrolysis, and gasification Efficient use of biomass with the desired output and minimizing the drawbacks are the core of the research, and marginal focus is being held on developing new techniques The variety of composition and uptake of different elements throughout the lifespan of biomass produces a mixture of results In general, it can be seen that the optimization was observed either in the form of chemical looping combustion to prevent greenhouse gas emission or in upgrading of bio-oil to produce biofuels The significant factor is the reaction co

A Combined Overview of Combustion, Pyrolysis, and Gasification of Biomass

A rapid growth in biodiesel production has naturally led to a surplus of crude glycerol generated. Due to the impurities present in the crude glycerol, expensive refining processes are often necessary in order for the crude glycerol to be used in the same applications as pure glycerol. As a result, the demand for crude glycerol is quite low, and biodiesel producers must find ways to dispose it. Disposal can be costly, detrimental to the environment, and wasteful. Exploration of crude glycerol utilization is of significance for not only reducing the negative impact on the environment but also for increasing the economic benefits of biodiesel production. This paper reviewed a number of valuable and practical applications of crude glycerol in the sector of renewable energy generation through processes such as fermentation, digestion, gasification, pyrolysis, liquefaction, combustion, and steam reforming. Studies indicated that an integration of crude glycerol to other systems for energy production is a promising option despite the impurities in crude glycerol, and some processes even benefit from their presence.

Utilization of the residual glycerol from biodiesel production for renewable energy generation

Paracetamol (acetaminophen) (PAR), caffeine (CAF) and tramadol hydrochloride (TRA) are important drugs widely used for many clinical purposes. Determination of their contents is of the paramount interest. In this respect, a quick, simple and sensitive isocratic RP-HPLC method with photodiode array detection was developed for the determination of paracetamol, caffeine and tramadol in pharmaceutical formulations. An improved sensitive procedure was also evolved for tramadol using a fluorescence detector system. A C18 column and a mobile phase constituted by methanol/phosphate were used. LODs were found to be 0.2 μg/mL, 0.1 μg/mL and 0.3 μg/mL for paracetamol, caffeine and tramadol hydrochloride, respectively, using photodiode-array detection. Alternatively, LOD for tramadol decreased to 0.1 μg/mL with the fluorescence detector. Other notable analytical figures of merit include the linear concentration ranges, 0.8-270 μg/mL, 0.4-250 μg/mL and 1.0-300 (0.2-40) μg/mL, for the same ordered analytes (including the fluorescence detector). The proposed method was successfully applied for the quantitative determination of the three drugs in tablet dosage forms.

Development and Validation of an RP-HPLC-PDA Method for Determination of Paracetamol, Caffeine and Tramadol Hydrochloride in Pharmaceutical Formulations

The purpose of this research article is to provide a comprehensive method of evaluation for public transportation. In this sense, this study considers transport lines that offer in Ciudad Juarez, Chihuahua. Hence, this study presents a description of the public transport system as part of the literature review. Likewise, the document describes an appropriate model based on the more outstanding publications about urban mobility and public transportation for passengers. Nevertheless, it is based on the Pythagorean Fuzzy combinative distance-based assessment (CODAS) to analyze and evaluate the alternatives through criteria that define general performance. Thus, the integration of these methods provides an adequate methodology for decision-making concerning urban planning and mobility to detect and improve the performance of criteria not considered within sustainable urban mobility plans. Results show how the applied approach can work as a powerful tool for the appraisal of the transport service. Finally, the results give relevant information to the local authority of the transport management of Ciudad Juarez to do improvements focused on the user.

https://www.mdpi.com/2071-1050/13/3/1281/pdf

Assessment Urban Transport Service and Pythagorean Fuzzy Sets CODAS Method: A Case of Study of Ciudad Juárez

A techno-economic study of HTC processes coupled with power facilities and oxy-combustion systems

Clinical Outcomes of Transcatheter Arterial Embolization for Secondary Stiff Shoulder

Herein, we report a computational database for the complexes of alkali [Li(I), Na(I), K(I)] and alkaline-earth [Be(II), Mg(II) and Ca(II)] cations with 25 small ligands with varying charge and donor atoms ("O", "N", and "S") that provides geometries and accurate bond energies useful to analyze metal-ligand interactions in proteins and nucleic acids. The role of the ligand→metal charge transfer, the equilibrium bond distance, the electronegativity of the donor atom, the ligand polarizability, and the relative stability of the complexes are discussed in detail. The interacting quantum atoms (IQA) method is used to decompose the binding energy into electrostatic and quantum mechanical contributions. In addition, bond energies are also estimated by means of multipolar electrostatic calculations. No simple correlation exists between bond energies and structural/electronic descriptors unless the data are segregated by the type of ligand or metal. The electrostatic attraction of some molecules (H2 O, NH3 , CH3 OH) towards the metal cations is well reproduced using their (unrelaxed) atomic multipoles, but the same comparison is much less satisfactory for other ligands (e. g. benzene, thiol/thiolate groups, etc.). Besides providing reference structures and bond energies, the database can contribute to validate molecular mechanics potentials capable of yielding a balanced description of alkali and alkaline-earth metals binding to biomolecules.

/pdf/alkali-and-alkaline-earth-cations-in-complexes-with-small-4rqatsh2z2.pdf

R. López

Papers

Development and Validation of an RP-HPLC-PDA Method for Determination of Paracetamol, Caffeine and Tramadol Hydrochloride in Pharmaceutical Formulations

Assessment Urban Transport Service and Pythagorean Fuzzy Sets CODAS Method: A Case of Study of Ciudad Juárez

A techno-economic study of HTC processes coupled with power facilities and oxy-combustion systems

Clinical Outcomes of Transcatheter Arterial Embolization for Secondary Stiff Shoulder

Alkali and Alkaline-Earth Cations in Complexes with Small Bioorganic Ligands: Ab Initio Benchmark Calculations and Bond Energy Decomposition.