The use of conductivity measurements in organic solvents for the characterisation of coordination compounds

A dilute solution parameter obtained from static light-scattering measurements is proposed as a predictor for protein crystallization experiments. The osmotic second virial coefficients, B22, have been measured for a variety of proteins in solvents that are known to promote crystallization and the values for B22 were found to lie within a fairly narrow range which we refer to as a crystallization slot. Solution conditions which were known not to favor crystallization of the proteins resulted in B22 values well outside the crystallization slot.

Predicting protein crystallization from a dilute solution property

Organotin(IV) N,N-disubstituted dithiocarbamates

13C and 119Sn NMR Study of some four- and five-coordinate triphenyltin(IV) compounds

119Sn Chemical Shifts in five- and six-coordinate organotin chelates

Synthesis, Structure, and Bonding of Complexes of Dimethyl- and Diphenyltin Ions With Bidentate Ligands1

Synthesis of .beta.-diketonate chelates of the bis(cyclopentadienyl)titanium(IV) moiety: infrared and proton magnetic resonance spectra

Hydrolysis of the Aquo Ions R3Sn+ and R2Sn+: Steric Effects on the Dissociation of Aquo Acids

Isolation of complex halo anions as the acetylacetonatobis(cyclopentadienyl)titanium(IV) and -vanadium(IV) salts. Reactions of bis(.pi.-cyclopentadienyl)titanium(IV) and bis(.pi.-cyclopentadienyl)vanadium(IV) with squarate and ethyl acetoacetate ions

The equilibria between neodymium hydroxide, hydrogen ions, and hydroxide ions were studied by measuring the solubility of the neodymium hydroxide in dilute hydrochloric and perchloric acids, neutral water, and sodium hydroxide solutions. Data on equilibrium constants and free energy changes are presented, and to confirm conclusions drawn from the solubility data, the hydrolysis of the trivalent ions of neodymium and praseodymium were studied, basing the hydrolysis constant on the hydrogen ion concentration at which the hydrolysis began.

The Thermodynamic Properties of Neodymium Hydroxide Nd(OH)3, in Acid, Neutral and Alkaline Solutions at 25°; the Hydrolysis of the Neodymium and Praseodymium Ions, Nd3+, Pr3+

R. Stuart Tobias

Papers

Synthesis, Structure, and Bonding of Complexes of Dimethyl- and Diphenyltin Ions With Bidentate Ligands1

Synthesis of .beta.-diketonate chelates of the bis(cyclopentadienyl)titanium(IV) moiety: infrared and proton magnetic resonance spectra

Hydrolysis of the Aquo Ions R3Sn+ and R2Sn+: Steric Effects on the Dissociation of Aquo Acids

Isolation of complex halo anions as the acetylacetonatobis(cyclopentadienyl)titanium(IV) and -vanadium(IV) salts. Reactions of bis(.pi.-cyclopentadienyl)titanium(IV) and bis(.pi.-cyclopentadienyl)vanadium(IV) with squarate and ethyl acetoacetate ions

The Thermodynamic Properties of Neodymium Hydroxide Nd(OH)3, in Acid, Neutral and Alkaline Solutions at 25°; the Hydrolysis of the Neodymium and Praseodymium Ions, Nd3+, Pr3+