R
Raymond Y. N. Ho
Researcher at University of Minnesota
Publications - 35
Citations - 3135
Raymond Y. N. Ho is an academic researcher from University of Minnesota. The author has contributed to research in topics: Raman spectroscopy & Catalysis. The author has an hindex of 23, co-authored 35 publications receiving 3014 citations. Previous affiliations of Raymond Y. N. Ho include Leiden University & University of California, Los Angeles.
Papers
More filters
Journal ArticleDOI
Dioxygen Activation by Enzymes with Mononuclear Non-Heme Iron Active Sites
Lawrence Que,Raymond Y. N. Ho +1 more
Journal ArticleDOI
An FeIV=O complex of a tetradentate tripodal nonheme ligand.
Mi Hee Lim,Mi Hee Lim,Jan Uwe Rohde,Audria Stubna,Michael R. Bukowski,Miquel Costas,Raymond Y. N. Ho,Eckard Münck,Wonwoo Nam,Lawrence Que +9 more
TL;DR: It is proposed that the FeIVO species derives from O—O bond heterolysis of an unobserved FeII(TPA)-acyl peroxide complex, and lends credence to the proposed participation of analogous species in the oxygen activation mechanisms of many mononuclear nonheme iron enzymes.
Journal ArticleDOI
End-on and side-on peroxo derivatives of non-heme iron complexes with pentadentate ligands: models for putative intermediates in biological iron/dioxygen chemistry.
Gerard Roelfes,Vladislav Vrajmasu,Kui Chen,Raymond Y. N. Ho,Jan Uwe Rohde,Charon Zondervan,Rene M. La Crois,Ebe P. Schudde,Martin Lutz,Anthony L. Spek,Ronald Hage,Ben L. Feringa,Eckard Münck,Lawrence Que +13 more
TL;DR: The synthesis and characterization of a series of iron(II) complexes with pentadentate N5 ligands that react with H( 2)O(2) to generate transient low-spin Fe(III)-OOH intermediates is reported, with first metrical details of the iron-peroxo units in this family of complexes revealed.
Journal ArticleDOI
Metal Complex-Catalyzed Epoxidation of Olefins by Dioxygen with Co-Oxidation of Aldehydes. A Mechanistic Study
TL;DR: It is concluded that the principal role of the metal complexes is to aid in the initiation step for the free radical autoxidation of the aldehyde and that acylperoxy radicals generated in the Autoxidation reaction (or metal complexes formed by complexation of the acyl peroxy radicals) are the active epoxidizing agents.