Porphyrins and related macrocycles have been intensively exploited as sensing materials in chemical sensors, since in these devices they mimic most of their biological functions, such as reversible binding, catalytic activation, and optical changes. Such a magnificent bouquet of properties allows applying porphyrin derivatives to different transducers, ranging from nanogravimetric to optical devices, also enabling the realization of multifunctional chemical sensors, in which multiple transduction mechanisms are applied to the same sensing layer. Potential applications are further expanded through sensor arrays, where cross-selective sensing layers can be applied for the analysis of complex chemical matrices. The possibility of finely tuning the macrocycle properties by synthetic modification of the different components of the porphyrin ring, such as peripheral substituents, molecular skeleton, coordinated metal, allows creating a vast library of porphyrinoid-based sensing layers. From among these, one can...

Porphyrinoids for Chemical Sensor Applications.

■ CONTENTS Books, Reviews, and Articles of General Interest 488 Sensors for (Dissolved) Gases and Vapors 489 Hydrogen 489 Hydrocarbons 490 Oxygen 491 Ammonia 493 Carbon Dioxide 494 Nitrogen Oxides 494 Vapors of Organic Solvents 495 Sensors for Humidity, Water Fractions, Hydrogen Peroxide, and Hydrazine 495 Humidity 495 Water Fractions 496 Hydrogen Peroxide and Hydrazine 496 Sensors for pH Values, Ions, and Salinity 496 pH Values 496 Ions 497 Salinity and Ionic Strength 499 Sensors for Organic Species 499 Biosensors 500 Immunosensors 500 PNA-Based Biosensors (DNA, Aptamers) 501 Other Affinity Sensors 501 Enzymatic Biosensors 502 Whole Cell Sensors 502 Advanced Optical Sensing Schemes and Materials 503 Author Information 505 Corresponding Author 505 Notes 505 Biographies 505 Acknowledgments 505 References 505

Fiber-Optic Chemical Sensors and Biosensors (2008–2012)

Xu-dong Wang*,† and Otto S. Wolfbeis*,‡ †Department of Chemistry, Fudan University, 200433 Shanghai, P. R. China ‡Institute of Analytical Chemistry, Chemoand Biosensors, University of Regensburg, D-93040 Regensburg, Germany ■ CONTENTS Books, Reviews, and Articles of General Interest 204 Sensors for (Dissolved) Gases and Vapors 204 Hydrogen 204 Hydrocarbons 206 Oxygen 206 Carbon Dioxide 208 Nitrogen Oxides 208 Other Gases 208 Ammonia 209 Ethanol 209 Other Volatile Organic Compounds (VOC)s 210 Sensors for Humidity, Water Fractions, Hydrogen Peroxide, and Hydrazine 211 Humidity 211 Water Fractions in Organic Solvents 212 Hydrogen Peroxide 213 Sensors for pH Values, Ions, and Salinity 213 pH Values 213 Ions 214 Salinity and Ionic Strength 215 Sensors for Organic Species 216 Glucose Sensing 216 Sucrose 217 Oils 217 Other Organics 217 Biosensors 218 Nucleic Acid-Based Biosensors (DNAand Aptamer-Based) 218 Immunosensors 218 Enzymatic Biosensors 219 Other Biosensors 220 New Schemes and Materials 220 New Sensing Schemes 220 Molecularly Imprinted Polymer (MIP)-Based Sensors 221 Photonic Crystals 223 Author Information 223 Corresponding Authors 223 Notes 223 Biographies 223 Acknowledgments 223 References 223

Fiber-Optic Chemical Sensors and Biosensors (2013-2015).

Architecture and development of the Neurospora crassa hypha -- a model cell for polarized growth.

https://iopscience.iop.org/article/10.1088/2040-8986/aac68d/pdf

Biomedical application of optical fibre sensors

The infusion, flow and cure of RTM6 resin in a carbon fibre reinforced composite preform have been monitored using a variety of multiplexed fibre optic sensors. Optical fibre Fresnel sensors and tilted fibre Bragg grating (TFBG) sensors were configured to monitor resin infusion/flow in-plane of the component. The results obtained from the different sensors were in good agreement with visual observations. The degree of cure was monitored by Fresnel sensors via a measurement of the refractive index of the resin which was converted to degree of cure using a calibration determined from Differential Scanning Calorimetry. Fibre Bragg grating sensors fabricated in highly linearly birefringent fibre were used to monitor the development of transverse strain during the cure process, revealing through-thickness material shrinkage of about 712 μe and residual strain of 223 μe. An alternative approach to infusion monitoring, based on an array of multiplexed tapered optical fibre sensors interrogated using optical frequency domain reflectometry, was also investigated in a separate carbon fibre preform that was infused with RTM6 resin.

Multiplexed fibre optic sensors for monitoring resin infusion, flow, and cure in composite material processing

Tapered optical fibers with nano-assembled coatings of thicknesses of order tens of nanometres were used for the detection of ammonia gas. The film coating was composed of alternate layers of tetrakis-(4-sulfophenyl) porphine (TSPP) and poly(allylamine hydrochloride) (PAH), which were deposited using the electrostatic self-assembly process (ESA). Exposure of a PAH/TSPP nano-assembled non-adiabatic tapered optical fiber with a waist diameter of 10 µm to ammonia induced significant optical changes in the transmission spectrum of the optical fiber. The fiber optic sensor showed a linear sensitivity to the concentration of ammonia in the range of 10–100 ppm, with response and recovery times less than 100 and 240 sec, respectively. The 3σ limit of detection (LOD) was estimated to be ca. 2 ppm.

/pdf/optical-gas-sensor-fabrication-based-on-porphyrin-anchored-2n6u1iyxjq.pdf

Optical Gas Sensor Fabrication Based on Porphyrin-Anchored Electrostatic Self-Assembly onto Tapered Optical Fibers

Nanostructured coatings have been deposited onto tapered optical fibres using the Langmuir–Blodgett technique. The response of the transmission spectrum of the tapered fibres to changes in thickness of the coating has been analysed. The effects observed are shown to be dependent on the diameter of the tapered region.

https://iopscience.iop.org/article/10.1088/0957-0233/20/3/034001/pdf

Response of the transmission spectrum of tapered optical fibres to the deposition of a nanostructured coating

The use of high spatial resolution optical frequency domain reflectometry (OFDR) to facilitate the multiplexing of a serial array of tapered optical fibre sensors is presented. Changes in the attenuation of the Rayleigh backscattered signal from the tapered regions are used to monitor the refractive index of the surrounding medium. The use of an array of five tapered regions to monitor liquid flow is demonstrated. An analysis of the performance of the system shows that, for tapers of diameter 50??m, up to nine tapers could be multiplexed using commercial OFDR instrumentation.

/pdf/multiplexing-a-serial-array-of-tapered-optical-fibre-sensors-kpp3o05jie.pdf

Multiplexing a serial array of tapered optical fibre sensors using coherent optical frequency domain reflectometry

Nanostructured coatings have been deposited onto tapered optical fibres using the Langmuir Blodgett technique. The
response of the transmission spectrum of the tapered fibres to changes in thickness of the coating has been analysed. The
effects observed are shown to be dependent on the diameter of the tapered region.

Renata Jarzebinska

Papers

Multiplexed fibre optic sensors for monitoring resin infusion, flow, and cure in composite material processing

Optical Gas Sensor Fabrication Based on Porphyrin-Anchored Electrostatic Self-Assembly onto Tapered Optical Fibers

Response of the transmission spectrum of tapered optical fibres to the deposition of a nanostructured coating

Multiplexing a serial array of tapered optical fibre sensors using coherent optical frequency domain reflectometry

Response of the transmission spectrum of tapered optical fibres to the deposition of a nanostructured coating