Showing papers by "Richard D. Adams published in 2020"
TL;DR: All new products, 2-8, were characterized structurally by single-crystal X-ray diffraction analyses and eliminated the NMe3 grouping, reversibly, when heated to yield the ethyne cluster complex Ru6C(CO)15(μ3-C2H2), 5, and the butadiendiyl cluster complexRu6(μ6-C)(CO)17, 1, which contains the terminally coordinated zwitterionic ligand.
Abstract: Ru6(μ6-C)(CO)17, 1, has been shown to react with C2H2 when activated by Me3NO to yield the complexes Ru6C(CO)15(μ–η2-C2H2NMe3), 2, and Ru6C(CO)14(μ3–η4-C4H4NMe3), 3, containing a bridging 2-trimeth...
6 citations