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Richard J. Saykally
Researcher at University of California, Berkeley
Publications - 459
Citations - 42709
Richard J. Saykally is an academic researcher from University of California, Berkeley. The author has contributed to research in topics: Spectroscopy & Absorption spectroscopy. The author has an hindex of 94, co-authored 457 publications receiving 40997 citations. Previous affiliations of Richard J. Saykally include University of California & Lawrence Berkeley National Laboratory.
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Journal ArticleDOI
pH-dependent x-ray absorption spectra of aqueous boron oxides
Andrew M. Duffin,Craig P. Schwartz,Alice H. England,Janel S. Uejio,David Prendergast,Richard J. Saykally +5 more
TL;DR: Simulations reveal that water is arranged nearly isotropically around boric acid and sodium borate, but the calculations also indicate that the boron K-edge NEXAFS spectra are insensitive to hydrogen bonding, molecular environment, or salt interactions.
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The high resolution infrared spectrum and molecular structure of the superacid H2F+ by velocity modulation laser absorption spectroscopy
TL;DR: In this paper, the gas phase infrared spectrum of the fluoronium ion (H2F+) was recorded with Doppler-limited resolution between 3080 and 3520 cm−1 by velocity modulation laser absorption spectroscopy of a hydrogen plasma containing 5% HF.
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Hydrogen bond breaking dynamics of the water trimer in the translational and librational band region of liquid water.
Frank N. Keutsch,Ray S. Fellers,M. G. Brown,Mark R. Viant,and Poul B. Petersen,Richard J. Saykally +5 more
TL;DR: These are the first experiments that provide a detailed molecular picture of the respective motions without extensive interpretation of tau(H) on intermolecular motions for liquid water via computer simulations.
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Electrokinetic Hydrogen Generation from Liquid Water Microjets
TL;DR: In this article, a method for generating molecular hydrogen directly from the charge separation effected via rapid flow of liquid water through a metal orifice, wherein the input energy is the hydrostatic pressure times the volume flow rate, was described.
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A study of the ν1 fundamental and bend‐excited hot band of DNN+ by velocity modulation absorption spectroscopy with an infrared difference frequency laser
TL;DR: In this article, the combination of the ac discharge velocity modulation technique with cw tunable difference frequency infrared generation and dual beam subtraction of laser amplitude noise produces an extremely sensitive (10−6 absorbance/Hz1/2) direct absorption method for observing vibrational spectra of molecular ions.